Updated on 2024/03/30

写真a

 
SANDA,Fumio
 
Organization
Faculty of Chemistry, Materials and Bioengineering Professor
Title
Professor
Contact information
メールアドレス
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Degree

  • 博士(工学) ( 1994.7 )

Research Areas

  • Nanotechnology/Materials / Polymer chemistry

Education

  • Kyoto University   Graduate School, Division of Engineering

    1987

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  • Kyoto University   Faculty of Engineering

    - 1985

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  • Kyoto University   Graduate School, Division of Engineering

    1987

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Professional Memberships

Committee Memberships

  • 日本化学会   Chemistry Letters Associate Editor  

       

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  •   日本接着学会誌編集委員長;理事;会員  

       

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  •   Chemistry Letters Associate Editor;会員  

       

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  •   会員  

       

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  • 日本接着学会   日本接着学会誌編集委員長  

       

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  • 日本接着学会   理事  

       

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Papers

  • Preparation and Catalytic Function of Substituted Polyacetylenes Coordinated to Palladium Nanoclusters Reviewed

    Masahide Goto, Marina Nakaoka, Tatsuki Nagata, Takeyuki Suzuki, Hideya Kawasaki, Yasushi Obora, Hiromitsu Sogawa, Fumio Sanda

    ネットワークポリマー論文集   44, 6, 275–285   2023.11

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    Poly(4-ethynylaniline) [poly(1)] coordinated to palladium nanoclusters (Pd NCs) were prepared. The coordination of Pd NCs was confirmed by X-ray photoelectron spectroscopy and scanning transmission electron microscopy. Pd NCs were coordinated with the benzene rings as well as amino groups of poly(1). Pd NCs were partly coordinated with the polymers, maintaining their original size to form the aggregates with sizes of several tens to hundreds nanometers. Pd NCs coordinated with poly(1) efficiently served as catalysts for the Mizoroki-Heck and Suzuki-Miyaura cross-coupling reactions.

    DOI: 10.11364/networkedpolymer.44.6_275

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  • Control of Higher-Order Structures of Platinum-Containing Conjugated Polymers by Ligand Exchange Reactions: Chirality Transfer from Optically Active Ligands to Optically Inactive Polymers Reviewed

    Takahiro Ishida, Taichi Sotani, Natsuhiro Sano, Hiromitsu Sogawa, Fumio Sanda

    Macromolecules   55, 309–321   2021.11

  • Tyrosine-based photoluminescent diketopiperazine supramolecular aggregates. International journal

    Noritaka Shimosaraya, Taichi Sotani, Yu Miyagi, Evan Angelo Quimada Mondarte, Kasinan Suthiwanich, Tomohiro Hayashi, Yuuya Nagata, Hiromitsu Sogawa, Fumio Sanda

    Soft matter   18, 137–145 ( 1 )   137 - 145   2021.11

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    Language:English   Publishing type:Research paper (scientific journal)  

    L-Tyrosine diketopiperazine (DKP) derivative 1 was synthesized, and the aggregation and photoluminescence behaviors were examined. A solution of 1 in tetrahydrofuran (THF) gradually became viscous at room temperature, and turned into the gel state 5 hours after preparation, as confirmed by dynamic viscoelasticity measurement. A solution of 1 in THF exhibited photoluminescence. Fibrous patterns were observed by transmission electron, atomic force and fluorescence microscopies. Dynamic light scattering, semiempirical molecular orbital and density functional theory calculations, as well as molecular dynamics simulations, indicated aggregate formation. This was attributed to intermolecular hydrogen bonding, mainly between the DKP moieties and partly between the urethane moieties, resulting in π-orbital overlap of the terminal phenyl groups leading to photoluminescence.

    DOI: 10.1039/D1SM01206A

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  • Photo-Triggered Chiroptical Switching of Platinum Complexes Bearing Azobenzene Moieties Reviewed

    Shinichi Iba, Kohei Iwata, Taichi Sotani, Takahiro Ishida, Natsuhiro Sano, Hiromitsu Sogawa, Fumio Sanda

    Organometallics   40, 3550–3559   2021.10

  • Main-chain type benzoxazine polymers consisting of polypropylene glycol and phenyleneethynylene units: spacer effect on curing behavior and thermomechanical properties Reviewed

    Takumi Kobayashi, Masanobu Muraoka, Masahide Goto, Masaki Minami, Hiromitsu Sogawa, Fumio Sanda

    Polymer Journal   54, 133–141 ( 2 )   133 - 141   2021.10

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    Publishing type:Research paper (scientific journal)  

    Benzoxazine polymers containing phenyleneethynylene and polypropylene glycol (PPG) in the main chain, poly(1)230, poly(1)400 and poly(1)2000, were synthesized by a Mannich reaction of the corresponding ethynylenebisphenol, paraformaldehyde and PPG diamines with Mn = 230–2,000. The curing temperature of poly(1) decreased from 212 to 182 °C as the Mn of the PPG chain decreased from 2,000 to 230. Poly(1)230–2000 was heated at 200–250 °C to obtain the corresponding polymers, and poly(1)′230–2000 was cured by ring-opening polymerization of the benzoxazine moieties. The structures of the polymers were elucidated by 1H-NMR and IR spectroscopies before and after curing. Poly(1)′230–2000 became flexible upon increasing the Mn of the PPG chain. Poly(1)′230 showed Tg as high as 253 °C. Poly(1)′230–2000 was thermally stable at approximately 300 °C, presumably due to the existence of rigid phenyleneethynylene moieties.

    DOI: 10.1038/s41428-021-00568-x

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  • Highly Photoluminescent Poly(norbornene)s Carrying Platinum–Acetylide Complex Moieties in Their Side Chains: Evaluation of Oxygen Sensing and TTA–UC Reviewed

    Taichi Sotani, Toshiko Mizokuro, Tatsuo Yajima, Hiromitsu Sogawa, Fumio Sanda

    Polym. Chem.   12, 4829–4837   2021.8

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  • Reinvestigation of Thermal Isomerization of cis-Stereoregulated Poly(phenylacetylene) by Spectroscopic Study and DFT Calculation Reviewed

    Masahide Goto, Masaki Minami, Hiromitsu Sogawa, Fumio Sanda

    Polymer   229, 124013   2021.7

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  • Synthesis of Platinum-Containing Conjugated Polymers Bearing Optically Active Amide Groups: A Mechanistic Study of Chiral Aggregation Reviewed

    Taichi Sotani, Tatsuo Yajima, Hiromitsu Sogawa, Fumio Sanda

    Macromolecules   53, 11077–11088   2020.12

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  • Synthesis and Cross-Linking of a Benzoxazine-Containing Anthracene Moiety: Thermally Stable Photoluminescent Benzoxazine Resin Reviewed

    Masahide Goto, Tatsuo Yajima, Masaki Minami, Hiromitsu Sogawa, Fumio Sanda

    MACROMOLECULES   53, 6640-6648 ( 15 )   6640 - 6648   2020.7

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    Language:English   Publishing type:Research paper (scientific journal)   Publisher:AMER CHEMICAL SOC  

    A novel benzoxazine derivative, 9,10-bis(6-ethynyl-3-pheny1-3,4-dihydro-1,3-benzoxazine)anthracene (1a), was synthesized by the Sonogashira-Hagihara coupling reaction of 9,10-dibromoanthracene and 6-ethynyl-3-phenyl-3,4-dihydro-1,3-benzoxazine. A CH2Cl2 solution of 1a luminesced with a high quantum yield (Phi = 81%). Compound 1a afforded solventinsoluble cross-linked polybenzoxazine 1b by the bulk polymerization at 250 degrees C. Solution polymerization of a dilute solution of 1a at 200 degrees C afforded solvent-soluble samples, accompanied by a decrease of photoluminescence intensity. The weight loss values of 1a and 1b were 81 and 87%, respectively, under nitrogen at 500 degrees C. We believe that the present study will lead to thermally stable curing resins whose degree of curing can be estimated with the naked eye by observing the decrease of photoluminescence.

    DOI: 10.1021/acs.macromol.0c00910

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  • Synthesis of Platinum-Containing Conjugated Polymers Having QuinoxP* and Bipyridine Ligands. Chirality Transfer from the Phosphine Ligand to the Polymer Backbone Reviewed

    Manabu Marumoto, Taichi Sotani, Yu Miyagi, Tatsuo Yajima, Natsuhiro Sano, Fumio Sande

    MACROMOLECULES   53, 2031-2038 ( 6 )   2031 - 2038   2020.3

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    Language:English   Publishing type:Research paper (scientific journal)   Publisher:AMER CHEMICAL SOC  

    Platinum (Pt) containing novel conjugated polymers, poly(1-2a)-poly(1-2d) having bipyridine ligands were synthesized by the Sonogashira-Hagihara coupling polymerization of [Pt(4,4'-dibromo-2,2'-bipyridine)((R,R)-2,3-bis(tert-butylmethylphosphino)quinoxaline)(trifluoromethanesulfonate)(2)] (1) coordinated with 4,4'-dibromo-2,2'-bipyridine/(R,R)-2,3-bis(tert-butylmethylphosphino)quinoxaline [(R,R)-QuinoxP*] and 1,4-diethynylbenzene (2a), 1,4-diethynyl-2,5-bis(heptyloxy)benzene (2b), 1,4-diethynyl-2,5-bis(2-ethylhexyloxy)benzene (2c), and 1,4-diethynyl-2,5-bis(2-(2-methoxyethoxy)ethoxy)benzene (2d). Poly(1-2d) exhibited circular dichroism signals derived from (R,R)-QuinoxP* and the conjugated main chain around 290 and 440 nm in DMF, respectively. The simulated CD spectroscopic pattern of a low molecular model compound, M1-Pt, agreed well with the observed spectra. The TEM images of poly(1-2d) in the solid state exhibited dispersed patterns with sizes around 10 nm. Concentrated solutions of polymer 1-2d in DMF and CHCl3 partly exhibited patterns assignable to the formation of lyotropic liquid crystals.

    DOI: 10.1021/acs.macromol.0c00096

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  • 高分子の主鎖・側鎖間ネットワーク形成を活用する強靱化 Reviewed

    三田文雄

    日本接着学会誌   56, 74-80   2020.3

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  • "Synthesis and Photoisomerization Behavior of Polyamide‐phenyleneethynylenes Bearing Azobenzene Moieties in the Main Chain Reviewed

    Shinichi Iba, Takahiro Ishida, Fumio Sanda

    Polym. Bull.   77, 1121-1134   2020

  • Synthesis and Crosslinking Reaction of a Novel Polymer Containing Benzoxazine and Phenyleneethynylene Moieties in the Main Chain Reviewed

    Takumi Kobayashi, Masahide Goto, Masaki Minami, Fumio Sanda

    J. Polym. Sci., Part A: Polym. Chem.   57, 2581–2589   2019.11

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  • Synthesis, Chiroptical, and Redox Properties of Ferrocene-Containing Optically Active Polymers Reviewed

    Taichi Sotani, Hiroko Iwakiri, Hirotaka Yamada, Noritaka Shimosaraya, Yu Miyagi, Fumio Sanda

    Macromol. Mater. Eng.   304, 1900282   2019.8

  • Polymerization of Substituted Acetylenes Using Well-Defined Rhodium Complex Catalyst. Chirality Transfer and Amplification in Chiral-Chiral Block and Random Copolymers Reviewed

    Masahide Goto, Ayaka Nito, Yu Miyagi, Fumio Sanda

    Macromol. Mater. Eng.   304, 1900275   2019.7

  • Thermo-responsive Micelles Prepared from Brush-like Block Copolymers of Proline- and Oligo(lactide)-functionalized Norbornenes Reviewed

    Sutthira Sutthasupa, Kajornsak Faungnawakij, Kenneth B. Wagener, Fumio Sanda

    Polymer   177, 178–188   2019.5

  • Synthesis of block copolymers using end-functionalized polyacetylenes as macroinitiators Reviewed

    Masashi Shiotsuki, Kei Takahashi, Jesus Rodriguez Castanon, Fumio Sanda

    Polymer Chemistry   9, 3855-3863   3855 - 3863   2018.5

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    © The Royal Society of Chemistry. Polyacetylenes substituted with phenyl, N-tert-butoxycarbonyl-l-valine 4-anilide, and (S)-1-(acetoxy)ethyl groups with number-average molecular weights ranging from 3800 to 13 500 were synthesized by the polymerization of the corresponding acetylene monomers using [{1,1′-bis(diphenylphosphino)ferrocene}PdBr(C6H4-o-CH2OH)] as a catalyst. l-Lactide and γ-benzyl-l-glutamate N-carboxyanhydride were polymerized using the polyacetylenes as macroinitiators to obtain the block copolymers, some of which formed chiral secondary structures. A block copolymer consisting of helically twisted polyacetylene and α-helical peptide was successfully synthesized for the first time.

    DOI: 10.1039/c8py00598b

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  • Synthesis and Crosslinking Reaction of Polyacetylenes Substituted with Benzoxazine Rings: Thermally Highly Stable Benzoxazine Resins Reviewed

    Masahide Goto, Yu Miyagi, Masaki Minami, Fumio Sanda

    J. Polym. Sci., Part A: Polym. Chem.   56, 1884–1893   2018.5

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  • Effect of phosphine ligand on the optical absorption/emission properties of platinum-containing conjugated polymers Reviewed

    Yu Miyagi, Taichi Sotani, Tatsuo Yajima, Natsuhiro Sano, Fumio Sanda

    Polymer Chemistry   9, 1772–1779 ( 14 )   1772 - 1779   2018.2

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    Language:English   Publishing type:Research paper (scientific journal)   Publisher:Royal Society of Chemistry  

    The Sonogashira-Hagihara coupling polymerization of a d-hydroxyphenylglycine-derived diiodoarylene monomer and platinum-containing diethynylphenylene monomers with various substituents, HCC-C6H4-CC-Pt(PR3)2-CC-C6H4-CCH, 1: R = C4H9, 2: R = C8H17, 3: R = cyclohexyl, 4: R = phenyl, and 5: R = 4-methoxyphenyl, gave the corresponding polymers 1′-5′ with number-average molecular weights of 4600-22000. The polymers were soluble in CHCl3, CH2Cl2, THF and DMF. CD/UV-vis spectroscopic analysis and dynamic light scattering measurements revealed that 1′-5′ formed chirally regulated unimolecular structures in THF/toluene mixtures, while formed chiral aggregates in THF/MeOH mixtures. The conjugation of the polymer main chain was longer for monomers with aryl groups bonded to P compared to monomers with alkyl groups bonded to P. The relationship between the HOMO-LUMO gaps and phosphine ligands was reasonably explained by DFT calculations. The polymers exhibited photoluminescence with quantum yields ranging from 0.003% to 0.9%. The photoluminescence intensity was controlled by changing the phosphine substituents. The thermal stability of the polymers increased and the refractive index decreased as the alkyl chain length of the phosphine ligand was increased.

    DOI: 10.1039/c7py01886j

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  • Ligand Exchange Reaction for Controlling the Conformation of Platinum-Containing Polymers Reviewed

    Yu Miyagi, Takahiro Ishida, Manabu Marumoto, Natsuhiro Sano, Tatsuo Yajima, Fumio Sanda

    Macromolecules   51, 815-824 ( 3 )   815 - 824   2018.1

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    Language:English   Publishing type:Research paper (scientific journal)   Publisher:American Chemical Society  

    Control of the conformation of polymers can be achieved by the ligand exchange reaction of optically active poly(phenyleneethynylene) 1′ containing Pt(PPh3)2- moieties in the main chain. Polymer 1′ was reacted with 1,2-bis(diphenylphosphino)ethane (dppe), 1,3-bis(diphenylphosphino)propane (dppp), and 1,4-bis(diphenylphosphino)butane (dppb) to give the corresponding polymers 2′, 3′, and 4′ containing Pt(dppe)-, Pt(dppp)-, and Pt(dppb)- moieties in the main chain, respectively. Polymers 1′ and 2′ exhibited negligibly small circular dichroism (CD) signals in THF, indicating the absence of regulated chiral structures, while polymers 3′ and 4′ exhibited strong CD signals in THF. The dynamic light scattering (DLS) analysis of the polymer solutions indicated that polymer 3′ formed a chirally regulated one-handed helix intramolecularly bridged with dppp, and polymer 4′ formed aggregates intramolecularly and/or intermolecularly bridged with dppb.

    DOI: 10.1021/acs.macromol.7b02249

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  • Macroporous scaffolds: Molecular brushes based on oligo(lactic acid)–amino acid–indomethacin conjugated poly(norbornene)s

    Sutthira Sutthasupa, Fumio Sanda

    European Polymer Journal   98, 162–171   162 - 171   2018.1

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    Language:English   Publishing type:Research paper (scientific journal)   Publisher:Elsevier Ltd  

    Leucine-derived norbornene monomer (1), oligo(lactic acid)-derived norborne macromonomer (2) and indomethacin-conjugated norbornene (3) were synthesized and polymerized using the Grubbs ruthenium complex as a catalyst. Macromonomer 2 was synthesized by the ring-opening polymerization of lactide using 5-norbornene-2,3-exo,exo-dimethanol as an initiator and 1,8-diazabicyclo[5.4.0]undec-7-ene (DBU) as a catalyst. The corresponding polymers, poly(1), poly(2), poly(3) and copolymers with number-average molecular weights (Mn) ranging from 14 000 to 360 000 were obtained in 73–95% yields. Poly(2) formed scaffolds by simply drying under reduced pressure presumably due to the brush-like structure causing entanglement of the polymer chains. The compressive strength of poly(2) scaffold increased as increasing the polylactide chain length. The compressive strength of the scaffolds obtained from the copolymers ranged from 0.222 to 0.587 MPa in accordance with the monomer unit ratios. SEM revealed the presence of pores around 5–10 µm diameters, together with larger pores dispersed in the range of 50–300 µm diameters. TEM demonstrated the presence of polymer networks. The conjugated indomethacin was gradually released by incubation under acidic condition (pH 5.7) at 37 °C. The results of % cell viability, release of LDH activity and cell morphology assays revealed that the obtained scaffolds did not exhibit cytotoxicity toward HEK 293 cells.

    DOI: 10.1016/j.eurpolymj.2017.11.020

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  • Synthesis of Phenyleneethynylene Macrocycle Bearing Optically Active Amide Groups Undergoing Reversible Sol−Gel Transformation

    Tatsuya Ogawa, Taichi Sotani, Yu Miyagi, Fumio Sanda

    Network Polymer   38, 242–249   2017.12

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  • Synthesis of Novel Optically Active Poly(thiophenyleneethynylenephenylene)s. Effects of Chirality Competition and Cooperation at the Side Chains on Higher Order Structures Reviewed

    Yu Miyagi, Yoshinori Otaki, Yuki Takahashi, Fumio Sanda

    Polymer   130, 250–257   2017.10

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  • Synthesis and Properties of Amino Acid-based Optically Active Poly(benzoxazine)s

    Yu Miyagi, Masahide Goto, Masaki Minami, Fumio Sanda

    J. Adhes. Soc. Jpn.   53, 338–347   2017.10

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  • Transformer of Achiral Amounts to Chirality: Double Reversal of Enantioselectivity Using a Single Cocatalyst in Asymmetric Polymerization

    Guanwu Yin, Geng Zhang, Toshiki Aoki, Masahiro Teraguchi, Takashi Kaneko, Jesus Rodriguez Castanon, Masashi Shiotsuki, Fumio Sanda

    Macromolecules   50, 7468–7474   2017.9

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  • Sonogashira–Hagihara and Mizoroki–Heck Coupling Polymerizations Catalyzed by Pd Nanoclusters

    Shizuka Asada, Ayaka Nito, Yu Miyagi, Junya Ishida, Yasushi Obora, Fumio Sanda

    Macromolecules   50, 4083–4087   2017.5

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  • Polymerization of Optically Active Disubstituted Acetylene Monomers by Pd Catalyst Bearing Bulky Phosphine Ligand

    Yuta Goto, Yu Miyagi, Natsuhiro Sano, Fumio Sanda

    J. Polym. Sci., Part A: Polym. Chem.   55, 3011–3016   2017.3

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  • Synthesis of Poly(1-chloro-2-arylacetylene)s with High Cis-Content and Examination of Their Absorption/Emission Properties Reviewed

    Jesus Rodriguez Castanon, Natsuhiro Sano, Masashi Shiotsuki, Fumio Sanda

    J. Polym. Sci., Part A: Polym. Chem.   55, 382-388   2017.1

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  • Synthesis of Diblock Copolymers of Indomethacin/Aspartic Acid Conjugated Norbornenes and Characterization of Their Self-Assembled Nanostructures as Drug Carriers Reviewed

    Sutthira Sutthasupa, Fumio Sanda

    Eur. Polym. J.   85, 211-224   2016.10

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  • Synthesis and Properties of Novel Optically Active Platinum-containing Poly(phenyleneethynylene)s

    Yoshinori Otaki, Manabu Marumoto, Yu Miyagi, Takehiro Hirao, Takeharu Haino, Fumio Sanda

    Chem. Lett.   45, 937–939   2016.5

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  • Synthesis of Platinum-Containing Poly(phenyleneethynylene)s Having Various Chromophores: Aggregation and Optical Properties

    Yu Miyagi, Yuno Shibutani, Yoshinori Otaki, Fumio Sanda

    Polym. Chem.   7, 1070–1078   2016.1

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  • Synthesis of Optically Active Conjugated Polymers Containing Platinum in the Main Chain: Control of the Higher-Order Structures by Substituents and Solvents Reviewed

    Yu Miyagi, Takehiro Hirao, Takeharu Haino, Fumio Sanda

    J. Polym. Sci., Part A: Polym. Chem.   53, 2452-2461   2015.8

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  • Chirality Amplification in Helical Block Copolymers. Synthesis and Chiroptical Properties of Block Copolymers of Chiral/Achiral Acetylene Monomers

    Shohei Kumazawa, Jesus Rodriguez Castanon, Masashi Shiotsuki, Takahiro Sato, Fumio Sanda

    Polym. Chem.   6, 5931-5939   2015.7

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  • 水素結合を駆動力とするネットワークポリマーの構築と構造制御 Reviewed

    三田文雄

    ネットワークポリマー   36, 148-154   2015.6

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  • Polymerization of a Disubstituted Acetylene Using Palladium Catalysts

    Jesus Rodriguez Castanon, Yukako Murayama, Natsuhiro Sano, Fumio Sanda

    Chem. Lett.   44, 1200-1201   2015.6

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  • Synthesis and Properties of Novel Optically Active Poly(thiophenyleneethynylene-phenyleneethynylene)s

    Yoshinori Otaki, Yu Miyagi, Fumio Sanda

    Chem. Lett.   44, 1013-1015   2015.4

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  • Controlled Polymerization of Phenylacetylenes Using Well-Defined Rhodium Catalysts

    Fumio Sanda, Masashi Shiotsuki, Toshio Masuda

    Macromol. Symp.   350, 67-75   2015.4

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  • Synthesis and Copolymerization of Oligo(Lactic Acid) Derived Norbornene Macromonomers With Amino Acid Derived Norbornene Monomer: Formation of the 3D Macroporous Scaffold Reviewed

    Sutthira Sutthasupa, Fumio Sanda, Kajornsak Faungnawakij, Puttinan Meepowpa

    J. Polym. Sci., Part A: Polym. Chem.   53, 1660-1670   2015.3

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  • Photoinduced Formation of an Azobenzene-Based CD-Active Supramolecular Cyclic Dimer Reviewed

    Hiromitsu Sogawa, Kayo Terada, Yu Miyagi, Masashi Shiotsuki, Yoshihito Inai, Toshio Masuda, Fumio Sanda

    Chem. Eur. J.   21, 6747-6755   2015.3

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  • Synthesis and Polymerization of Phenylacetylene Having Two Carbazole Units and Properties of the Formed Polymer Reviewed

    Natsuhiro Sano, Kazuki Banzai, Shigeki Naka, Hiroyuki Okada, Fumio Sanda

    J. Polym. Sci., Part A: Polym. Chem.   53, 1245-1251   2015.2

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  • Well-definedなパラジウム錯体触媒を用いる置換アセチレンの重合 Reviewed

    Jesus Rodriguez Castanon, 宮城 雄, 大滝善永, 三田文雄

    高分子論文集   72, 208-217   2015.2

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  • Synthesis and Properties of Poly(phenyleneethynylene)s Bearing Perylene Moieties at the Side Chains

    Akinobu Hashimoto, Yu Miyagi, Hiromitsu Sogawa, Shunsuke Yamamoto, Fumio Sanda

    Chem. Lett.   43, 1622-1624   2014.10

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  • Synthesis and Helical Structures of Poly(ω-alkynamide)s Having Chiral Side Chains: Effect of Solvent on Their Screw-Sense Inversion Reviewed

    Yuji Suzuki, Yu Miyagi, Masashi Shiotsuki, Yoshihito Inai, Toshio Masuda

    Chem. Eur. J.   20, 15131-15143   2014.9

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  • Synthesis of Optically Active Conjugated Polymers Bearing m-Terphenylene Moieties by Acetylenic Coupling Polymerization: Chiral Aggregation and Optical Properties of the Product Polymers Reviewed

    Yu Miyagi, Hiromitsu Sogawa, Masashi Shiotsuki, Fumio Sanda

    Macromolecules   47, 1594-1603   2014.2

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  • New Approach to the Polymerization of Disubstituted Acetylenes by Bulky Monophosphine-Ligated Palladium Catalysts

    Jesus Rodriguez Castanon, Natsuhiro Sano, Masashi Shiotsuki, Fumio Sanda

    ACS Macro Lett.   3, 51-54   2014.1

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  • Synthesis of Novel Optically Active Poly(phenyleneethynylene–aryleneethynylene)s Bearing Hydroxy Groups. Examination of the Chiroptical Properties and Conjugation Length

    Hiromitsu Sogawa, Yu Miyagi, Masashi Shiotsuki, Fumio Sanda

    Macromolecules   46, 8896–8904   2013.11

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  • Synthesis of Optically Active Poly(m-phenyleneethynylene-aryleneethynylene)s Bearing Hydroxy Groups and Examination of the Higher Order Structures

    Hiromitsu Sogawa, Masashi Shiotsuki, Takehiro Hirao, Takeharu Haino, Fumio Sanda

    Macromolecules   46, 8161-8170   2013.10

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  • Synthesis and Photoresponse of Helically Folded Poly(phenyleneethynylene)s Bearing Azobenzene Moieties in the Main Chains Reviewed

    Hiromitsu Sogawa, Masashi Shiotsuki, Fumio Sanda

    Macromolecules   46, 4378-4387   2013.5

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  • Helix-sense-selective Polymerization of Achiral Acetylene Monomer Catalyzed by Rh Zwitterionic Complexes with Tethered Chiral Amino and Ether Groups Reviewed

    Naoya Onishi, Toshiki Aoki, Takashi Kaneko, Masahiro Teraguchi, Natsuhiro Sano, Toshio Masuda, Masashi Shiotsuki, Fumio Sanda

    Chem. Lett.   42, 278-280   2013.2

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  • Polymerization of Phenylacetylenes Using Rhodium Catalysts Coordinated by Norbornadiene Linked to a Phosphino or Amino Group Reviewed

    Naoya Onishi, Masashi Shiotsuki, Toshio Masuda, Natsuhiro Sano, Fumio Sanda

    Organometallics   32, 846-853   2013.1

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  • Characterization of the Polymerization Catalyst [(2,5-norbornadiene)Rh{C(Ph)=CPh2}(PPh3)] and Identification of the End Structures of Poly(phenylacetylenes) Obtained by Polymerization Using This Catalyst Reviewed

    Shohei Kumazawa, Jesus Rodriguez Castanon, Naoya Onishi, Keiko Kuwata, Masashi Shiotsuki, Fumio Sanda

    Organometallics   31, 6834-6842   2012.9

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  • Synthesis of End-Functionalized Polyacetylenes that Contain Polar Groups by Employing Well-Defined Palladium Catalysts Reviewed

    Jesus Rodriguez Castanon, Keiko Kuwata, Masashi Shiotsuki, Fumio Sanda

    Chem. Eur. J.   18, 14085-14093   2012.9

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  • alpha-Propargyl Amino Acid-Derived Optically Active Novel Substituted Polyacetylenes: Synthesis, Secondary Structures, and Responsiveness to Ions

    Hiromitsu Sogawa, Masashi Shiotsuki, Fumio Sanda

    J. Polym. Sci. Part A: Polym. Chem.   50, 2008-2018   2012.5

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  • Stabilization of Higher-Order Structure of Poly(phenyleneethynylene)s by Metathesis Polymerization at the Side Chains Reviewed

    Akinobu Hashimoto, Hiromitsu Sogawa, Masashi Shiotsukiwa, Fumio Sanda

    Polymer   53, 2559-2566   2012.4

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Books

  • 白金含有共役高分子の合成と構造制御

    宮城 雄, 三田文雄

    日本接着学会誌  2017.5 

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  • 置換ポリアセチレンの精密合成 Reviewed

    三田文雄( Role: Sole author)

    高分子  2016.9 

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  • Polyacetylenes

    Fumio Sanda( Role: Contributor)

    Shiro Kobayashi, Klaus Müllen, Eds., Encyclopedia of Polymeric Nanomaterials, Springer-Verlag, Berlin Heidelberg  2015.1 

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  • Transition Metal Containing Polymers

    Fumio Sanda( Role: Contributor)

    Shiro Kobayashi, Klaus Müllen, Eds., Encyclopedia of Polymeric Nanomaterials, Springer-Verlag, Berlin Heidelberg  2015.1 

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  • Substituted Polyacetylenes Reviewed

    Fumio Sanda, Masashi Shiotsuki, Toshio Masuda( Role: Contributor)

    Conjugated Polymers: A Practical Guide to Synthesis, Klaus Mullen, John R. Reynolds, Toshio Masuda Eds., Royal Society of Chemistry (Cambridge, UK)  2014.1 

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  • 後周期遷移金属錯体触媒を用いる置換アセチレンの重合機構の解析

    Jesus Rodriguez Castanon, 三田文雄

    国共同利用版広報, センター共同研究報告 (平成24年度)  2013.12 

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  • 光学活性フェニレンエチニレン系共役高分子の合成と高次構造制御

    三田文雄( Role: Sole author)

    関西大学理工学会誌 理工学と技術  2013.8 

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  • Alkyne Polymerization Reviewed

    Fumio Sanda, Masashi Shiotsuki, Toshio Masuda( Role: Contributor)

    Krzysztof Matyjaszewski and Marcus Mueller Eds., Polymer Science: A Comprehensive Reference, Elsevier BV (Amsterdam)  2012.12 

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  • 分子軌道法計算による光学活性高分子の構造解析

    曽川洋光, 三田文雄

    全国共同利用版広報, センター共同研究報告 (平成23年度)  2012.12 

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Awards

  • 日本接着学会賞

    2019.6   日本接着学会  

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    Country:Japan

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  • 合成樹脂工業協会 学術賞

    2014.4   合成樹脂工業協会  

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    Country:Japan

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  • 日本接着学会進歩賞

    2005.4   日本接着学会  

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    Country:Japan

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  • 有機合成化学協会富士写真フイルム研究企画賞

    2002.4   有機合成化学協会  

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    Country:Japan

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  • コニカ画像科学奨励賞

    2002.4   コニカ画像科学振興財団  

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    Country:Japan

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  • 合成樹脂工業協会学術奨励賞

    1999.4   合成樹脂工業協会  

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    Country:Japan

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  • 中村研究賞

    1997.4   手島工業教育資金団  

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    Country:Japan

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