2024/03/30 更新

写真a

シミズ トモヒロ
清水 智弘
SHIMIZU,Tomohiro
所属
システム理工学部 教授
職名
教授
連絡先
メールアドレス
外部リンク

学位

  • 博士(工学)

研究分野

  • ナノテク・材料 / ナノ材料科学

所属学協会

  • ナノ学会

    2021年4月

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  • Microprocess and Nanotechnology Conference

    2018年4月

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  • 応用物理学会

    2011年4月 - 2014年3月

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  • Material research society

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委員歴

  • ナノ構造・物性 副部会長  

    2021年4月   

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  • 論文委員  

    2018年4月   

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  • MNC Program Committee Member  

    2018年4月   

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  • 応用物理学会 プログラム編集委員  

    2011年4月 - 2014年3月   

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  • プログラム編集委員  

    2011年4月 - 2014年3月   

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論文

  • Fluorescence Intensity of Liposomes and <i>E. coli</i> Attached to Nanopillar Arrays: Implications for Bacterial Death on Nanostructures

    Masato Daimon, Yushi Yanagisawa, Kenta Ishibashi, Yukihiro Tominari, Shukichi Tanaka, Hiroaki Kojima, Tomohiro Shimizu, Shoso Shingubara, Takeshi Ito

    ACS Applied Nano Materials   6 ( 3 )   1610 - 1619   2023年1月

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    掲載種別:研究論文(学術雑誌)   出版者・発行元:American Chemical Society (ACS)  

    DOI: 10.1021/acsanm.2c04489

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  • Fabrication and UV photoresponse of ordered ZnO nanonets using monolayer colloidal crystal template

    Yusuke Kiyomi, Naoya Shiraiwa, Takuto Nakazawa, Akihiro Fukawa, Kaito Oshio, Koichi Takase, Takeshi Ito, Shoso Shingubara, Tomohiro Shimizu

    Micro and Nano Engineering   16   100160 - 100160   2022年8月

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    掲載種別:研究論文(学術雑誌)   出版者・発行元:Elsevier BV  

    DOI: 10.1016/j.mne.2022.100160

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  • Bactericidal effect of nanostructures <i>via</i> lytic transglycosylases of <i>Escherichia coli</i>

    Soma Mimura, Tomohiro Shimizu, Shoso Shingubara, Hiroaki Iwaki, Takeshi Ito

    RSC Advances   12 ( 3 )   1645 - 1652   2022年

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    掲載種別:研究論文(学術雑誌)   出版者・発行元:Royal Society of Chemistry (RSC)  

    The time profiles of active cell ratios depended on the growth phase and the absence of some lytic transglycosylases of E. coli. Significant cell damage was not found on the autolysis inhibition condition.

    DOI: 10.1039/d1ra07623j

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  • Detailed analysis of liposome adsorption and its rupture on the liquid-solid interface monitored by LSPR and QCM-D integrated sensor 査読

    ASAI N, MATSUMOTO N, YAMASHITA I, SHIMIZU T, SHINGUBARA S, ITO T

    Sensing and Bio-Sensing Research   32, 100415   2021年

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  • Formation of Ultrathin Segregated-Ge Crystal on Al/Ge(111) Surface 査読

    KOBAYASHI K, OHTA A, KUROSAWA K, ARAIDAI M, TAOKA N, SHIMIZU T, IKEDA M, MAKIHARA K, MIYAZAKI S

    Jpn. J. Appl. Phys.   50, SGGK15   2020年

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  • Electrochemical Impedance Spectroscopy Study of Liposome Adsorption and Rupture on Self-Assembled Monolayer: Effect of Surface Charge 査読

    FUJINO Y, NAKAMURA R, HAN H W, YAMASHITA I, SHIMIZU T, SHINGUBARA S, ITO T

    Journal of Electroanalytical Chemistry   878,114572   2020年

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  • Observation of ultra-high energy density state with x-ray free electron laser SACLA 査読

    MAEDA Y, HIRONAKA Y, IWASAKI T, KAWASAKI K, SAKAWA Y, IZUMI T, OTA M, EGASHIRA S, NAKAGWA Y, NIGASHI N, SENTOKU Y, KODAMA R, OZAKI N, MATSUOKA T, SOMEKAWA T, YABUUCHI T, INUBUHI Y, TOGASHI T, KON A, SUEDA K, MIYANISHI K, SHINGUBARA S, SHIMIZU T, OKUMURA A, SHIGEMORI K

    High Energy Density Physics   36, 100813   2020年

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  • Formation of MoS2 nanostructure arrays using anodic aluminum oxide template 査読

    OKAMOTO T, SHIMIZU T, TAKASE K, ITO T, SHINGUBARA S

    Micro and Nano Engineering   9, 100071   2020年

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  • Nano-honeycomb electrode based QCM sensor and its application for PPI detection 査読

    ASAI N, MATSUMOTO N, KAZAMA N, NAGAOKA Y, SUMIYOSHI T, SHIMIZU T, SHINGUBARA S, ITO T

    IEEE Sensors Journal   19, 4025-4030   2019年

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  • Effect of additives on preparation of vertical holes in Si substrate using metal-assisted chemical etching 査読

    SHIMIZU T, NIWA R, ITO T, SHINGUBARA S

    Jpn. J. Appl. Phys.   58, SDDF06-1-4   2019年

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  • Effect of a metal interlayer under Au catalyst for the preparation of microscale holes in Si substrate by metal-assisted chemical etching 査読

    SHIMIZU T, NIWA R, ITO T, SHINGUBARA S

    Jpn. J. Appl. Phys.   58, SAAE07-1-5   2019年

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  • Evaluation of the interdiffusion properties of Cu and electroless-plated CoWB barrier films formed on silicon substrate 査読

    ISERI T, SHINDO S, MIYACHI Y, HIRATE A, SHIMIZU T, ITO T, TANAKA S, SHINGUBARA S

    Jpn. J. Appl. Phys.   57, 07MB02   2018年7月

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  • Switching behavior of resistive change memory using oxide nanowires 査読

    AONO T, SUGAWA K, SHIMIZU T, SHINGUBARA S, TAKASE K

    Jpn. J. Appl. Phys.   57, 02HD07   2018年6月

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  • Hf layer thickness dependence of resistive switching characteristics of Ti/Hf/HfO2/Au resistive random access memory device 査読

    NAKAJIMA R, AZUMA A, YOSHIDA H, SHIMIZU T, ITO T, SHINGUBARA S

    Jpn. J. Appl. Phys.   57, 02HD06   2018年6月

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  • Highly sensitive quartz crystal microbalance based biosensor using Au dendrite structure

    Naoto Asai, Hideaki Terasawa, Tomohiro Shimizu, Shoso Shingubara, Takeshi Ito

    Japanese Journal of Applied Physics   57 ( 2 )   2018年2月

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    記述言語:英語   掲載種別:研究論文(国際会議プロシーディングス)   出版者・発行元:Japan Society of Applied Physics  

    A Au dendrite structure was obtained by only electroplating under a suitable potential. A blanch like nanostructure was formed along the crystal orientation. In this study, we attempted to fabricate a Au dendrite structure on the electrode of a quartz crystal by electroplating to increase the specific surface area. We estimated the effective surface area by cyclic voltammetry (CV) and monitored the frequency shift induced by antigen-antibody interaction by the quartz crystal microbalance (QCM) method. The dendrite structure with the largest surface area was formed under -0.95 V for 5 min. In the measurement of the antigen-antibody interaction, the frequency shifts of 40, 80, and 110 Hz were obtained with the dendrite structured QCM chips formed at the above potential for 1, 1.5, and 2.0 min, respectively. The sensitivity was improved compared with that QCM chip having a flat surface electrode.

    DOI: 10.7567/JJAP.57.02CD01

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  • Voltage pulse induced resistance change response of ReRAM with HfO2 layer 査読

    AZUMA A, NAKAJIMA R, YOSHIDA H, SHIMIZU T, ITO T, SHINGUBARA S

    ECS Transactions   86, 13-21   2018年

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  • Fabrication of highly sensitive QCM sensor using AAO nanoholes and its application in biosensing 査読

    ASAI N, SHIMIZU T, SHINGUBARA S, ITO T

    Sensors and Actuators B   276, 534-539   2018年

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  • Nonenzymatic detection of glucose using BaCuO2 Thin layer 査読

    ITO T, ASADA T, ASAI N, SHIMIZU T, SHINGUBARA S

    Jpn. J. Appl. Phys. IOP PUBLISHING LTD   56, 01AH02   2017年5月

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  • Fabrication and characterization of nano porous lattice biosensor using anodic aluminum oxide substrate

    伊藤健, 松田祐貴, 神馬孝俊, 浅井直人, 清水智弘, 新宮原正三

    IOP PUBLISHING LTD,JAPANESE JOURNAL OF APPLIED PHYSICS   56, 06GG02   2017年5月

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  • Sensitized mass change detection using Au nanoporous electrode for biosensing 査読

    ASAI N, TERASAWA H, SHIMIZU T, SHINGUBARA S, ITO T

    IOP PUBLISHING LTD,Jpn. J. Appl. Phys.   56, 06GG04   2017年5月

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  • Fabrication and Characterization of Nano-Porous Lattice Biosensor Using Anodic Aluminum Oxide Substrate 査読

    ITO T, MATSUDA Y, JINBA T, ASAI N, SHIMIZU T, SHINGUBARA S

    Jpn. J. Appl. Phys.   56, 06GG02   2017年5月

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  • Antibacterial property of Si nanopillar array fabricated using metal assisted etching; Mimic a cicada wing

    T. Ito, K. Nakade, N. Asai, T. Shimizu, S. Shingubara

    ECS Transactions   75 ( 53 )   1 - 5   2017年

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    記述言語:英語   掲載種別:研究論文(国際会議プロシーディングス)   出版者・発行元:Electrochemical Society Inc.  

    We focused on a cicada wing which has superhydrophobic surface, antireflection to the light, unique tribology, and antibacterial property. From the SEM view, circular truncated cones in nanoscale were widely spread with regularly. It was just like nanopillar array. After the signature pattern was analyzed, we mimicked its structure composed of Si. Si nanostructure was fabricated mainly by wet process to decrease the cost but its dimension was controllable. We reported antibacterial property of the structure. Fabricated Si nanopillar array showed antibacterial property to E. Coli.

    DOI: 10.1149/07553.0001ecst

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  • Fabrication and optical property of metal nanowire arrays embedded in anodic porous alumina membrane

    Kouichi Takase, Tomohiro Shimizu, Kosuke Sugawa, Takashige Aono, Yuma Shirai, Tomohiko Nishida, Shoso Shingubara

    JAPANESE JOURNAL OF APPLIED PHYSICS   55 ( 6 )   2016年6月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)   出版者・発行元:IOP PUBLISHING LTD  

    Nanowires embedded in nanopores are potentially tough against surface scraping and agglomeration. In this study, we have fabricated Au and Ni nanowires embedded into anodic porous alumina (APA) and investigated their reflectance to study the effects of surface plasmon absorption properties and conversion from solar energy to thermal energy. Au nanowires embedded into APA show typical gold surface plasmon absorption at approximately 530 nm. On the other hand, Ni nanowires show quite a low reflectance under 600 nm. In the temperature elevation test, both Au and Ni nanowire samples present the same capability to warm up water. It means that Ni nanowires embedded into APA have almost the same photothermal activity as Au nanowires. (C) 2016 The Japan Society of Applied Physics

    DOI: 10.7567/JJAP.55.06GH09

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  • Oxidation of CuSn alloy nanotree and application for gas sensors

    Naoto Kaneko, Tomohiro Shimizu, Yoshihiro Tada, Shoso Shingubara

    JAPANESE JOURNAL OF APPLIED PHYSICS   55 ( 6 )   2016年6月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)   出版者・発行元:IOP PUBLISHING LTD  

    The CuSn alloy nanotree formed by DC electroplating is a true three-dimensional (3D) structure with many branches that separate the trunk perpendicularly. We carried out the oxidation of CuSn nanotrees in atmosphere in order to study the possibility of such nanotrees for application to sensors. It was confirmed that the oxygen concentration in the CuSn nanotree oxide increased with temperature and reached 40 at.% at 350 degrees C. The optical reflectance spectra of the CuSn nanotree oxide formed at 250 degrees C showed a 3-4% reflectance in the wavelength range between 400 and 900 nm, and its behavior differed from those of Cu and Sn oxides formed at 250 degrees C. The temperature dependence of electrical resistivity for the CuSn nanotree oxide showed a typical semiconductor behavior. By the introduction of H-2, O-2, N-2, and CO gases into the chamber, the resistance of the CuSn nanotree oxide responded against H-2 most sensitively, as well as against O-2 and CO gases. From the resistance change tendency, it is strongly suggested that the CuSn nanotree oxide is a p-type semiconductor, because it shows an increase in conductivity caused by the adsorption of a negative charge such as O-. However, the conductivity decreases with the adsorption of a positive charge such as H+. The present study suggests the high potential of the CuSn nanotree oxide as a gas sensor, since it has a very high surface-to-volume ratio. (C) 2016 The Japan Society of Applied Physics

    DOI: 10.7567/JJAP.55.06GH08

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  • Formation of three-dimensional nano-trees with perpendicular branches by electrodeposition of CuSn alloy

    Tomohiro Shimizu, Yoshihiro Tada, Naoto Kaneko, Shukichi Tanaka, Shoso Shingubara

    SURFACE & COATINGS TECHNOLOGY   294   83 - 89   2016年5月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)   出版者・発行元:ELSEVIER SCIENCE SA  

    Three-dimensional nano-tree-like structures consisting of single-crystalline CuSn alloy nanowires branching perpendicularly from their parent branches were observed. The nano-trees were formed by constant potential co-electrodeposition of Cu and Sn. The geometry of the branches had a four-fold symmetry around the parent branch, which originated from the crystalline structure of the mother CuSn crystal. XRD and TEM analysis revealed that the nanowire branches consisted of single-crystalline gamma-CuSn with &lt; 100 &gt; preferred growth directions. The addition of polyethylene glycol (PEG) with a molecular weight of 1000 in the plating bath is essential for the formation of the nano-tree structure. It is speculated that adsorbed PEG molecules on CuSn crystal planes with high Miller indices suppress CuSn alloy deposition, enhancing anisotropic growth of the CuSn crystal to form the nano-tree structure. (C) 2016 Elsevier B.V. All rights reserved.

    DOI: 10.1016/j.surfcoat.2016.03.046

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  • Polarized hard X-ray photoemission system with micro-positioning technique for probing ground-state symmetry of strongly correlated materials

    Hidenori Fujiwara, Sho Naimen, Atsushi Higashiya, Yuina Kanai, Hiroshi Yomosa, Kohei Yamagami, Takayuki Kiss, Toshiharu Kadono, Shin Imada, Atsushi Yamasaki, Kouichi Takase, Shintaro Otsuka, Tomohiro Shimizu, Shoso Shingubara, Shigemasa Suga, Makina Yabashi, Kenji Tamasaku, Tetsuya Ishikawa, Akira Sekiyama

    JOURNAL OF SYNCHROTRON RADIATION   23   735 - 742   2016年5月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)   出版者・発行元:INT UNION CRYSTALLOGRAPHY  

    An angle-resolved linearly polarized hard X-ray photoemission spectroscopy (HAXPES) system has been developed to study the ground-state symmetry of strongly correlated materials. The linear polarization of the incoming X-ray beam is switched by a transmission-type phase retarder composed of two diamond (100) crystals. The best value of the degree of linear polarization was found to be -0.96, containing a vertical polarization component of 98%. A newly developed low-temperature two-axis manipulator enables easy polar and azimuthal rotations to select the detection direction of photoelectrons. The lowest temperature achieved was 9 K, offering the chance to access the ground state even for strongly correlated electron systems in cubic symmetry. A co-axial sample monitoring system with long-working-distance microscope enables the same region on the sample surface to be measured before and after rotation. Combining this sample monitoring system with a micro-focused X-ray beam by means of an ellipsoidal Kirkpatrick-Baez mirror (25 mu m x 25 mu m FWHM), polarized valence-band HAXPES has been performed on NiO for voltage application as resistive random access memory to demonstrate the micro-positioning technique and polarization switching.

    DOI: 10.1107/S1600577516003003

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  • Fabrication of nanocone arrays by two step metal assisted chemical etching method

    Tomohiro Shimizu, Norihiro Tanaka, Yoshihiro Tada, Yasuhiro Hara, Noriaki Nakamura, Junichi Taniuchi, Koichi Takase, Takeshi Ito, Shoso Shingubara

    MICROELECTRONIC ENGINEERING   153   55 - 59   2016年3月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)   出版者・発行元:ELSEVIER SCIENCE BV  

    This work develops a novel method for preparing a moth eye structure, which has a sub-wavelength periodical Si nanocone structure on Si(100) substrate, using two-step metal assisted chemical etching (MACE). The 1st MACE and 2nd MACE were respectively performed with the intention to form perpendicular Si nanowire arrays on a Si substrate and sharpening the Si nanowire arrays. We found that the inhomogeneous absorption and aggregation of Au particles used as a catalyst for the 2nd MACE was important to obtain the nanocone shape. The obtained Si nanocone arrays showed superior anti-reflecting properties especially in a wavelength below 600 nm compared with the Si nanowire arrays. A possible mechanism involved in the formation of the nanocone structure by the 2 step MACE is discussed in this paper. (C) 2016 Elsevier B.V. All rights reserved.

    DOI: 10.1016/j.mee.2016.01.030

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  • Band gap tuning of Ni1-x MgxO films by radio-frequency sputter deposition for deep-ultraviolet photodetectors (vol 8, 105801, 2015)

    Hiroki Nishitani, Kohei Ohta, Sosuke Kitano, Ryosuke Hamano, Mitsuru Inada, Tomohiro Shimizu, Shoso Shingubara, Hiromitsu Kozuka, Tadashi Saitoh

    APPLIED PHYSICS EXPRESS   9 ( 3 )   2016年3月

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    記述言語:英語   出版者・発行元:IOP PUBLISHING LTD  

    DOI: 10.7567/APEX.9.039201

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  • Nitridation of silicon by nitrogen neutral beam

    Yasuhiro Hara, Tomohiro Shimizu, Shoso Shingubara

    APPLIED SURFACE SCIENCE   363   555 - 559   2016年2月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)   出版者・発行元:ELSEVIER SCIENCE BV  

    Silicon nitridation was investigated at room temperature using a nitrogen neutral beam (NB) extracted at acceleration voltages of less than 100 V. X-ray photoelectron spectroscopy (XPS) analysis confirmed the formation of a Si3N4 layer on a Si (100) substrate when the acceleration voltage was higher than 20V. The XPS depth profile indicated that nitrogen diffused to a depth of 36 nm for acceleration voltages of 60V and higher. The thickness of the silicon nitrided layer increased with the acceleration voltages from 20V to 60V. Cross-sectional transmission electron microscopy (TEM) analysis indicated a Si3N4 layer thickness of 3.1 nm was obtained at an acceleration voltage of 100V. Moreover, it was proved that the nitrided silicon layer formed by the nitrogen NB at room temperature was effective as the passivation film in the wet etching process. (C) 2015 Elsevier B.V. All rights reserved.

    DOI: 10.1016/j.apsusc.2015.11.096

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  • Fabricating a QCM device with the nanostructures using the AAO template

    N. Asai, T. Ito, T. Shimizu, S. Shingubara

    CHEMICAL SENSORS 12: CHEMICAL AND BIOLOGICAL SENSORS AND ANALYTICAL SYSTEMS   75 ( 16 )   229 - 232   2016年

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    記述言語:英語   掲載種別:研究論文(国際会議プロシーディングス)   出版者・発行元:ELECTROCHEMICAL SOC INC  

    The nano structure derived from Anodic Aluminum Oxide (AAO) is controllable by the anodizing conditions such as voltage, anodizing time, and the acid solutions. Regularly arranged nanopores were fabricated with high aspect ratio. We tried to use the nano structure as a template to build nanowire array on the quartz crystal to enlarge the surface area bond to analyte. Evaluating the shape of the nanowire, average of the height and the diameter of the nanowire were 1 mu m and 50 nm, respectively. In this case, high aspect ratio more than 20 was achieved. We fabricated nanowires on the electrode of the QCM chip and tried to detect the antigenantibody reaction.

    DOI: 10.1149/07516.0229ecst

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  • Antibacterial characteristics of Si nano-pillar array 査読

    Takeshi Ito, Kazuki Nakade, Naoto Asai, Tomohiro Shimizu, Shoso Shingubara

    2016 IEEE 16TH INTERNATIONAL CONFERENCE ON NANOTECHNOLOGY (IEEE-NANO)   82 - 84   2016年

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    記述言語:英語   掲載種別:研究論文(国際会議プロシーディングス)   出版者・発行元:IEEE  

    Cicada wings have nanostructures which shows superhydrophobic property, non reflecting to the light, and antibacterial characteristics. To mimic the nano structure of a cicada wing, we fabricated nano-pillar array using metal assisted etching. Fabricated nano-pillar array showed higher antibacterial property for E. coli. Our introduced process has advantages for industrial usage because of low cost and low environmental load based on wet process.

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  • Electrodeposited ZnO thin film on twin sensor QCM for sensing of ethanol at room temperature

    Takeshi Ito, Yudai Fujii, Noriyoshi Yamanishi, Naoto Asai, Tomohiro Shimizu, Shoso Shingubara

    PROCEEDINGS OF THE 30TH ANNIVERSARY EUROSENSORS CONFERENCE - EUROSENSORS 2016   168   411 - 414   2016年

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    記述言語:英語   掲載種別:研究論文(国際会議プロシーディングス)   出版者・発行元:ELSEVIER SCIENCE BV  

    QCM is one of major sensing methods for volatile organic compounds (VOC), however, the method is affected by environments such as temperature, humidity, and airflow. To cancel the signals affected by environments, we used twin sensor QCM which has two electrodes on one quartz substrate. In fact, one Au electrode was used as a reference, and ZnO thin film was electrodeposited on the other electrode to detect ethanol. The surface morphology of ZnO was changed corresponding to the applied potential on the electrodeposition. Scaly surface was obtained at -0.8 V vs. Ag/AgCl. QCM with scaly ZnO surface showed high frequency change on exposing to ethanol gas. (C) 2016 The Authors. Published by Elsevier Ltd.

    DOI: 10.1016/j.proeng.2016.11.192

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  • Magnetic conductive filament formed in the ReRAM device with ferromagnetic electrode

    Hayaco Yoshida, Tomohiro Shimizu, Takeshi Ito, Shoso Shingubara

    ECS Transactions   75 ( 32 )   65 - 71   2016年

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    記述言語:英語   掲載種別:研究論文(国際会議プロシーディングス)   出版者・発行元:Electrochemical Society Inc.  

    We studied magnetic conduction property of the conductive filament formed in the ReRAM device having two ferromagnetic electrodes. Anisotropic Magnetoresistance (AMR) property was observed in the ON-state of the devices, however, negative MR occurred for the one device and positive MR occurred for another devices, There were abrupt change of resistance around 250 mT for these devices. Micromagnetic simulation study strongly suggested that the abrupt change of MR was caused by the single domain switching of the magnetic conductive filament (MCF). Furthermore, it is suggested that typical MCF size was 40 x 40 x 4 nm1 by assuming that MCF was composed of Ni metals, It is also suggested that the difference of negative AMR and positive AMR is derived from the location of MCF. The present results suggest a possibility of new multilevel memory devices which can be operated by both electric field as well as magnetic field.

    DOI: 10.1149/07532.0065ecst

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  • Nitridation of Si surface at the bottom of submicron trench using nitrogen neutral beam

    Yasuhiro Hara, Tomohiro Shimizu, Shoso Shingubara

    JAPANESE JOURNAL OF APPLIED PHYSICS   54 ( 6 )   2015年6月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)   出版者・発行元:IOP PUBLISHING LTD  

    The nitridation of silicon at the bottom of nanoscale trench patterns using a nitrogen neutral beam (NB) extracted with a low acceleration voltage of less than 100 V was studied at room temperature. By X-ray photoelectron spectroscopy (XPS) analysis, the formation of a Si3N4 layer was confirmed at the bottom of the trench when the acceleration voltage was higher than 20 V. The XPS depth profile suggested that nitrogen was diffused to a depth of 180 nm. In contrast, the bottom of the trench was not nitrided by the low-energy N+ ions produced by inductively coupled plasma (ICP). It is suggested that most of the N+ ions bombarded the top corner of the trench owing to the concentrated electric field around it. On the other hand, the neutral N-2 or N beam was not affected by the local electric field concentration, and it was able to reach bottom of the deep trench. (C) 2015 The Japan Society of Applied Physics

    DOI: 10.7567/JJAP.54.06FH07

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  • Suppression of switching voltage variation by controlling filament formation in In/porous alumina/Al resistive change random access memory

    Yusuke Tanimoto, Shintaro Otsuka, Tomohiro Shimizu, Shoso Shingubara, Kouichi Takase

    JAPANESE JOURNAL OF APPLIED PHYSICS   54 ( 6 )   2015年6月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)   出版者・発行元:IOP PUBLISHING LTD  

    Resistive change memory has been expected to be a next generation memory due to high-speed response. However, wide variations of switching voltages are often found in the current-voltage (I-V) characteristics and hinder the practical applications. We have tried suppressing the variation by three tactics based on the filament model; confinement of conductive filaments, concentration of electric field, and preparation of many routes for conductive filaments with the same electrical properties. In this study, we have investigated the combination of concentration of electric field method and preparation of many routes for conductive filaments in the insulator by electrochemical treatment (ET) using sulfuric acid. The I-V curves depend on the ET time. The best result is obtained in the long ET time. With regards to switching voltage distribution, the combination of two methods provide better switching characters than those of single method. (C) 2015 The Japan Society of Applied Physics

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  • Magnetoresistance of conductive filament in Ni/HfO2/Pt resistive switching memory

    Shintaro Otsuka, Yoshifumi Hamada, Daisuke Ito, Tomohiro Shimizu, Shoso Shingubara

    JAPANESE JOURNAL OF APPLIED PHYSICS   54 ( 5 )   2015年5月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)   出版者・発行元:IOP PUBLISHING LTD  

    Ferromagnetic conductive filaments (CFs) were formed in a conductive-bridge random access memory (CBRAM) with a Ni electrode using high current compliances during a set process. We investigated CFs in a Ni/HfO2/Pt CBRAM using the current compliance dependences of the set process, low-temperature characteristics, and anisotropic magnetoresistance (AMR). Set processes occurred when a positive bias was applied to the Ni electrode only; therefore, the switching phenomena showed polarity. The resistance of the ON state (low resistance state) was dependent on the current compliance between 2 and 5 mA. The ON state of the device showed a metallic conduction property, suggested by the temperature dependence of resistance. When a high current compliance (5 mA) was used for programming, the ON state showed AMR, which was direct evidence of ferromagnetic CF formation. This suggests that the formation of a ferromagnetic CF is associated with the accumulation of Ni ions that diffused from the Ni electrode. The OFF-state (high resistance state) resistance slightly increased with decreasing temperature and AMR was not observed. (C) 2015 The Japan Society of Applied Physics

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  • Dynamic moderation of an electric field using a SiO2 switching layer in TaOx-based ReRAM

    Qi Wang, Yaomi Itoh, Tohru Tsuruoka, Shintaro Ohtsuka, Tomohiro Shimizu, Shoso Shingubara, Tsuyoshi Hasegawa, Masakazu Aono

    PHYSICA STATUS SOLIDI-RAPID RESEARCH LETTERS   9 ( 3 )   166 - 170   2015年3月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)   出版者・発行元:WILEY-V C H VERLAG GMBH  

    ReRAMs using oxygen vacancy drift in their resistive switching are promising candidates as next generation memory devices. One remaining issue is degradation of the on/off ratio down to 102 or less with an increased number of switching cycles. Such degradation is caused by a local hard breakdown in a set process due to a very high electric field formed just before the completion of a conductive filament formation. We found that introducing an ultra-thin SiO2 layer prevents the hard breakdown by dynamical moderation of the electric field formed in the TaOx matrix, resulting in repeated switching while retaining a higher on/off ratio of about 105. (C) 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim

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  • Stability evaluation of non-agglomerated Pd nanoparticle catalyst dispersion for electroless deposition

    Noriaki Nakamura, Junichi Taniuchi, Takayuki Sone, Kotoe Sasaki, Fumihiro Inoue, Tomohiro Shimzu, Shoso Shingubara

    ECS Transactions   64 ( 40 )   77 - 84   2015年

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    記述言語:英語   掲載種別:研究論文(国際会議プロシーディングス)   出版者・発行元:Electrochemical Society Inc.  

    We investigated the stability and adsorption properties of a Pd nanoparticles which are used for catalyst of electroless plating on dielectrics substrate. Some additives for Pd nanoparticle dispersion significantly improved the stability of the dispersion without deteriorating the adsorption of the Pd nanoparticles. Furthermore, the additives redispersed agglomerated Pd nanoparticles. These results suggest a method for applying Pd nanoparticles in manufacturing processes.

    DOI: 10.1149/06440.0077ecst

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  • Cu displacement plating on electroless plated CoWB layer on SiO&lt;inf&gt;2&lt;/inf&gt; and its adhesion property

    Kohei Ohta, Fumihiro Inoue, Tomohiro Shimizu, Shoso Shingubara

    ECS Transactions   64 ( 40 )   57 - 61   2015年

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    記述言語:英語   掲載種別:研究論文(国際会議プロシーディングス)   出版者・発行元:Electrochemical Society Inc.  

    For realizing high aspect ratio TSV with a low cost, the all-wet process utilizing electroless barrier and Cu-seed layers prior to Cu electroplated fill is one of the most promising methods. However, improvement of adhesion property of electroless plated barrier and seed layers on SiO&lt
    inf&gt
    2&lt
    /inf&gt
    has been intensively required. In this study, we studied displacement plating of Cu on electroless CoWB layer formed on SiO&lt
    inf&gt
    2&lt
    /inf&gt
    in an acidic bath. It turned out that displacement-plated Cu film grew with sacrifice of the partial CoWB layer, and showed a high adhesion strength that was enough to pass CMP process.

    DOI: 10.1149/06440.0057ecst

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  • Diffusion suppression in vapor-liquid-solid Si nanowire growth by a barrier layer between the Au catalyst and substrate

    Makoto Koto, Masatoshi Watanabe, Etsuko Sugawa, Tomohiro Shimizu, Shoso Shingubara

    JOURNAL OF CRYSTAL GROWTH   404   192 - 198   2014年10月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)   出版者・発行元:ELSEVIER SCIENCE BV  

    Nanowires have attracted significant interest because of their unique characteristics. Vapor-liquid-solid (VLS) growth is the standard method for fabricating nanowires and Au is the most commonly used catalyst. However, Au catalyst droplets diffuse over the Si substrate surface with a high migration velocity and agglomerate at relatively low temperatures. In our previous work, we reported a significant improvement in the positioning and diameter distribution of VLS-grown Si nanowires by inserting a diffusion barrier layer and concluded that the barrier layer suppressed the formation of AuSi eutectic droplets and prevented the droplets diffusing on the substrate surface during nucleation. In the present study, we analyzed the nucleation of the Au catalyst and examined its behavior during nucleation. Detailed multidirectional analysis and in situ observations confirmed that the formation and agglomeration of AuSi eutectic droplets was suppressed by the formation of a silicide layer. This because of the higher reaction temperatures between the diffusion barrier and the substrate silicon, and between the catalyst and the diffusion barrier, compared with the reaction between the Au catalyst and substrate silicon. (C) 2014 Elsevier B.V. All rights reserved.

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  • Effect of electric field concentration using nanopeak structures on the current – voltage characteristics of resistive switching memory

    OTSUKA S, SHIMIZU T, SHINGUBARA S, MAKIHARA K, MIYAZAKI S, YAMASAKI A, TANIMOTO Y, TAKASE K

    AIP Advance   4 ( 8 )   2014年8月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)  

    DOI: 10.1063/1.4892823

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  • Morphology dependence of optical reflectance properties for a high-density array of silicon nanowires

    Takuya Yamaguchi, Tomohiro Shimizu, Yasuhiro Morosawa, Koichi Takase, Tzu-Ling Chen, Shin-Ming Lu, Hui-Ching Chien, Shoso Shingubara

    JAPANESE JOURNAL OF APPLIED PHYSICS   53 ( 6 )   2014年6月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)   出版者・発行元:IOP PUBLISHING LTD  

    The dependence of reflectance on the morphology of Si nanowire (SiNW) arrays was investigated. Several samples including vertically aligned NW arrays and bunched NWs were prepared by a combination of a wet etching process and two types of drying process. The optical reflectance of the NW arrays depended on the length and aggregation degree of NWs. The bunched NW arrays with high aggregation degree reduced the reflectance to less than 8% in a long visible wavelength range. It is considered that the significant reduction in the reflectance of the bunched NWs is ascribed to the combination of the macrostructure with NWs. (C) 2014 The Japan Society of Applied Physics

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  • Effect of confining filaments on the current-voltage characteristics of resistive change memory by using anodic porous alumina

    Yusuke Tanimoto, Shintaro Otsuka, Tomohiro Shimizu, Shoso Shingubara, Tadataka Watanabe, Yoshiki Takano, Kouichi Takase

    JAPANESE JOURNAL OF APPLIED PHYSICS   53 ( 6 )   2014年6月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)   出版者・発行元:IOP PUBLISHING LTD  

    We have tried suppressing variation of switching voltages which hinder the practical application of resistive switching random access memory. On the basis of a filament model, fabrication of the top electrode with small enough size against the filament size and confining the filament are thought to be the solutions. In this study, we have investigated the confinement effects on the switching voltage variations using anodic porous alumina with ordered nano holes. Variation of the voltage has a trend to reduce with enlarging the diameters of nano holes by chemical etching. The confinement is very effective to improve the reproducibility of the switching voltages. (C) 2014 The Japan Society of Applied Physics

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  • Temperature dependence of resistance of conductive nanofilament formed in Ni/NiOx/Pt resistive switching random access memory

    Shintaro Otsuka, Yoshihumi Hamada, Tomohiro Shimizu, Shoso Shingubara

    JAPANESE JOURNAL OF APPLIED PHYSICS   53 ( 5 )   2014年5月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)   出版者・発行元:IOP PUBLISHING LTD  

    We investigated the resistive switching characteristics and temperature dependence of resistance of a Ni/NiOx/Pt resistive switching memory. The device was operated in a unipolar operation mode. From the temperature dependence of resistance, it is suggested that the conduction mechanism of the low-resistance state is metallic. Moreover, a deformed site that may correspond to the conductive filament appeared after the forming process. Cross-sectional transmission electron microscopy with energy dispersive X-ray analysis showed that the Ni atomic content at the NiOx of the deformed area was larger than those of other areas. It is strongly suggested that the conductive filament formed in the NiOx layer is composed of Ni atoms. (C) 2014 The Japan Society of Applied Physics

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  • Fabrication of vrtical Cu2ZnSnS4 nnowire arrays by two-step electroplating method into anodic aluminum oxide template”, J. Mater. 査読

    WANG C, TANAKA S, SHIMIZU T, SHINGUBARA S

    Sci. & Nanotech   1,1-4   2014年

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  • Fabrication of ordered arrays of anodic aluminum oxide pores with interpore distance smaller than the pitch of nano-pits formed by ion beam etching 査読

    WANG C, TANAKA S, SAITO K, SHIMIZU T, SHINGUBARA S

    J. Mater. Sci. & Nanotech.   1, 1-5   2014年

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  • Improvement of adhesion strength of electroless barrier layer and its application to TSV process

    Shoichiro Nishizawa, Fumihiro Inoue, Tomohiro Shimizu, Shoso Shingubara

    PROCESSING, MATERIALS, AND INTEGRATION OF DAMASCENE AND 3D INTERCONNECTS 5   58 ( 17 )   59 - 65   2014年

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    記述言語:英語   掲載種別:研究論文(国際会議プロシーディングス)   出版者・発行元:ELECTROCHEMICAL SOC INC  

    The all-wet process for TSV-fill utilizing electroless barrier and seed technologies prior to electroplating of Cu is promising methods to realize low-cost and highly reliable Cu-filled TSVs for 3-D integration of Si. Although there have been numerous studies to form electroless barrier layers such as Co- and Ni-alloys, poor adhesion of these barrier layers have been a serious problem. In this study, we studied effect of various additives on the adhesion strength of electroplated CoWB film. It is shown that addition of saccharine, which has both sulfone-and amino-groups, significantly improved adhesion strength.

    DOI: 10.1149/05817.0059ecst

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  • Ferromagnetic nano-conductive filament formed in Ni/TiO2/Pt resistive-switching memory

    Shintaro Otsuka, Yoshifumi Hamada, Tomohiro Shimizu, Shoso Shingubara

    Applied Physics A: Materials Science and Processing   118 ( 2 )   613 - 619   2014年

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    記述言語:英語   掲載種別:研究論文(学術雑誌)   出版者・発行元:Springer Verlag  

    There is a question whether the conductive filament (CF) formed in the oxide layer of a resistive-switching random access memory is made of oxygen vacancies or metallic atoms. We investigated the CF of Ni/TiO2/Pt device using temperature coefficient of resistance (TCR), anisotropic magnetoresistance (AMR), and cross-sectional transmission electron microscopy with energy dispersive X-ray analysis (TEM-EDX). The low resistance state (LRS) of the device showed metallic property by TCR measurement. Furthermore, the device in the LRS showed AMR, which was a direct evidence of the formation of ferromagnetic CF. The cross-sectional TEM-EDX observation revealed that a nano-sized Ni precipitation existed in the area nearby a conductive spot. It is intensively suggested that Ni atoms migrated from the adjacent Ni electrode to TiO2 layer to form the nano-sized ferromagnetic CF.

    DOI: 10.1007/s00339-014-8769-5

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  • Anisotropic magnetoresistance of ferromagnetic conductive filament in resistive switching memory

    S. Otsuka, Y. Hamada, T. Shimizu, S. Shingubara

    NONVOLATILE MEMORIES 3   64 ( 14 )   27 - 33   2014年

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    記述言語:英語   掲載種別:研究論文(国際会議プロシーディングス)   出版者・発行元:ELECTROCHEMICAL SOC INC  

    We report on an origin of the conductive filament (CF) for a Ni/HfO2/Pt resistive switching memory. The device shows SET process (from high to low resistance), when positive bias is applied to the Ni electrode. RESET process (from low to high resistance) occurs during both positive and negative biases. We investigated the temperature dependence of resistance and magnetoresistance for the low resistance states (LRS) of the device, which were formed with different amount of a current compliance. LRS formed with the high current compliance has a linear temperature dependence of resistance compared with that formed with the low current compliance. Moreover, anisotropic magnetoresistance was observed for the LRS, which was formed with the high current compliance. This suggests that CF is made of the ferromagnetic Ni atoms when a high current compliance was used to form LRS.

    DOI: 10.1149/06414.0029ecst

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  • Study on oxide thickness dependence of current-voltage characteristics for HfOx based ReRAM device

    Y. Hamada, S. Otsuka, T. Shimizu, S. Shingubara

    NONVOLATILE MEMORIES 3   64 ( 14 )   91 - 96   2014年

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    記述言語:英語   掲載種別:研究論文(国際会議プロシーディングス)   出版者・発行元:ELECTROCHEMICAL SOC INC  

    In this letter, we investigated HfOx thickness dependence of current-voltage characteristics and temperature dependence of resistance for Ni/HfOx/Pt resistance random access memory (ReRAM) device. There was a significant difference in switching properties between these devices whose oxide thicknesses differ only 1 or 2 nm. The devices showed bipolar resistive switching behaviors. The ON state resistance indicated a linear decrease of resistance with lowering temperature, which was typical for a metal. It should be noted that SET voltage as well as resistance of high resistance state increased almost linearly with increasing oxide thickness from 4.0 to 5.6 nm.

    DOI: 10.1149/06414.0093ecst

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  • Temperature Dependence of Resistance of Conductive Filament Formed by Dielectric Breakdown

    Shintaro Otsuka, Takashi Kato, Takuya Kyomi, Yoshifumi Hamada, Yoshihiro Tada, Tomohiro Shimizu, Shoso Shingubara

    JAPANESE JOURNAL OF APPLIED PHYSICS   52 ( 6 )   2013年6月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)   出版者・発行元:IOP PUBLISHING LTD  

    An investigation of current-voltage (I-V) characteristics and the temperature dependence of resistance in a resistive switching (RS) memory with a Cu/SiO2/Au device was performed. Moreover, conductive spots were observed by scanning electron microscopy (SEM) and cross-sectional transmission electron microscopy (TEM). Both unipolar and bipolar operation modes were obtained. From the temperature dependence of resistance, it is suggested that the conduction mechanism of the low resistance state (LRS) is metallic conduction and that of the high resistance state (HRS) is variable-range hopping (VRH) conduction. The results of observing the device support this suggestion. We propose the switching mechanism in the Cu/SiO2/Au device from these results. (c) 2013 The Japan Society of Applied Physics

    DOI: 10.7567/JJAP.52.06GF04

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  • Control of Crystal Orientation and Diameter of Silicon Nanowire Using Anodic Aluminum Oxide Template

    Tomohiro Shimizu, Fumihiro Inoue, Chonge Wang, Shintaro Otsuka, Yoshihiro Tada, Makoto Koto, Shoso Shingubara

    JAPANESE JOURNAL OF APPLIED PHYSICS   52 ( 6 )   2013年6月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)   出版者・発行元:IOP PUBLISHING LTD  

    The control of the crystal orientation and diameter of vertically grown epitaxial Si nanowires was demonstrated using a combination of a vapor-liquid-solid (VLS) growth technique and the use of an anodic aluminum oxide (AAO) template on a single-crystal Si substrate. The [100], [110], and [111] nanowires were selectively obtained by choosing the Si substrate with appropriate crystal orientation. The diameter of a Si nanowire in the AAO template could be controlled by the modification of the pore size of the AAO template with anodic voltage during anodization. (c) 2013 The Japan Society of Applied Physics

    DOI: 10.7567/JJAP.52.06GF06

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  • Improvement of the Reproducibility of the Switching Voltage of Resistance Change Random Access Memory by Restricting Formation of Conductive Filaments

    Saeko Furuya, Shintaro Otsuka, Tomohiro Shimizu, Shouso Shingubara, Tadataka Watanabe, Yoshiki Takano, Kouichi Takase

    JAPANESE JOURNAL OF APPLIED PHYSICS   52 ( 6 )   2013年6月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)   出版者・発行元:IOP PUBLISHING LTD  

    Resistance change random access memory (ReRAM) has been expected to be a next generation non-volatile memory. However, poor reproducibility of threshold voltage at which the dramatic change of the resistivity occurs hinders the practical application. We have attempted to improve the reproducibility of switching voltages using anodic porous alumina whose nanoholes are quite useful to restrict the filament forming area on the basis of the filament model. In this study, we have reported the pore size and film properties dependences of the variation width of the switching voltages. Two kinds of oxide films prepared by oxalic and sulfuric acids with two different anodic times were used as the insulating layer. Contrary to our expectation, just the sulfuric samples indicate good improvement about the switching voltages. Considering that the size of the effective contact area is not enough small against the filament size, the changing the film properties seems to be important for the suppressing the variation of switching voltages. (c) 2013 The Japan Society of Applied Physics

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  • Highly adhesive electroless barrier/Cu-seed formation for high aspect ratio through-Si vias

    Fumihiro Inoue, Tomohiro Shimizu, Hiroshi Miyake, Ryohei Arima, Toshihiko Ito, Hirofumi Seki, Yuko Shinozaki, Tomohiko Yamamoto, Shoso Shingubara

    MICROELECTRONIC ENGINEERING   106   164 - 167   2013年6月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)   出版者・発行元:ELSEVIER SCIENCE BV  

    A conformal diffusion barrier was formed in a high aspect ratio through-silicon via using electroless plating. Dense adsorption of Pd nanoparticle catalyst on SiO2 assisted the formation of a thin electroless Co-W-B layer, upon which an electroless Cu seed layer could be deposited. The adhesion strength of the Co-W-B film was enhanced by reducing the film thickness, and the maximum strength was obtained at a thickness of 20 nm. The Co-W-B layer exhibited good barrier properties against Cu diffusion to SiO2 after annealing at 300 degrees C, although slight diffusion of the Pd atoms in Cu was observed. (C) 2013 Elsevier B.V. All rights reserved.

    DOI: 10.1016/j.mee.2013.01.009

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  • Improved control of silicon nanowire growth by the vapor–liquid–solid method using a diffusion barrier layer between catalyst and substrate

    KOTO M, SHIMIZU T, SHINGUBARA S

    J. Crys. Growth   369   1 - 7   2013年4月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)  

    DOI: 10.1016/j.jcrysgro.2012.12.140

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  • Electric Conduction Mechanism of Resistive Switching Memory Fabricated with Anodic Aluminum Oxide

    S. Otsuka, T. Shimizu, S. Shingubara, N. Iwata, T. Watanabe, Y. Takano, K. Takase

    NONVOLATILE MEMORIES   50 ( 34 )   49 - 54   2013年

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    記述言語:英語   掲載種別:研究論文(国際会議プロシーディングス)   出版者・発行元:ELECTROCHEMICAL SOC INC  

    The electric conduction mechanism of electrochemically treated anodic aluminum oxide (AAO) resistance switching (RS) memory is investigated. The current-voltage characteristics of the AAO were measured for both of high resistance state and low resistant state at room temperature. The conduction mechanism of a high resistance state can be explained by separating into three regions of ohmic conduction, space charge limited current (SCLC), and Fowler-Nordheim (F-N) tunneling. It was suggested that the F-N tunneling deteriorates the reproducibility of switching voltages.

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  • Control of Adhesion Strength and TSV Filling Morphology of Electroless Barrier Layer

    R. Arima, F. Inoue, H. Miyake, T. Shimizu, S. Shingubara

    PROCESSING MATERIALS OF 3D INTERCONNECTS, DAMASCENE AND ELECTRONICS PACKAGING 4   50 ( 32 )   13 - 18   2013年

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    記述言語:英語   掲載種別:研究論文(国際会議プロシーディングス)   出版者・発行元:ELECTROCHEMICAL SOC INC  

    In this study, we investigated to control adhesion property of the electroless plated barrier layer on SiO2 by addition of saccharin and its deposition profile in a high aspect ratio TSV with inhibitor and saccharin. We achieved high adhesion strength of barrier layer by addition of suitable amount saccharin. Furthermore, we succeeded in the formation of thin continuous electroless barrier layer for a high aspect ratio TSV with addition of both inhibitor and saccharin. The proposed highly adhesive and conformal electroless barrier layer formation would provide a highly reliable all-wet TSV filling process.

    DOI: 10.1149/05032.0013ecst

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  • Temperature Dependence of Resistance in Conductive Filament Formed with Dielectric Breakdown of Ni/TiO2/Pt structure

    S. Otsuka, Y. Hamada, T. Shimizu, S. Shingubara

    NONVOLATILE MEMORIES 2   58 ( 5 )   27 - 31   2013年

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    記述言語:英語   掲載種別:研究論文(国際会議プロシーディングス)   出版者・発行元:ELECTROCHEMICAL SOC INC  

    We investigated resistive switching (RS) characteristics and temperature dependences of a resistance of the Ni/TiO2/Pt resistive switching memory. The device was operated in a unipolar mode. From the temperature dependence of resistance, it is shown that the conductive filament in the low resistance state (LRS) is metallic. Fabricated Pt/NiO/Pt RS memory to compare the RS characteristics showed similar RS phenomenon. The conductive mechanism of the Pt/NiO/Pt RS memory is also metallic. Temperature coefficients of resistance of various RS memory were compared.

    DOI: 10.1149/05805.0027ecst

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  • Adsorption of Pd nanoparticles catalyst in high aspect ratio through-Si vias for electroless deposition

    Fumihiro Inoue, Tomohiro Shimizu, Hiroshi Miyake, Ryohei Arima, Toshihiko Ito, Hirofumi Seki, Yuko Shinozaki, Tomohiko Yamamoto, Shoso Shingubara

    ELECTROCHIMICA ACTA   82   372 - 377   2012年11月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)   出版者・発行元:PERGAMON-ELSEVIER SCIENCE LTD  

    We studied electroless Co-W-B plating in through-Si vias (TSVs) using Pd nanoparticles (Pd-NPs) as a catalyst. The density of adsorbed Pd-NPs on SiO2 in the high aspect ratio TSVs was over 8500/mu m(2) after a long adsorption treatment. No Pd-NP agglomeration was observed. In contrast, agglomerates of large particles were observed after a conventional Sn-Pd colloid adsorption treatment. Using a Pd-NP catalyst, we succeeded in the formation of a thin continuous electroless Co-W-B barrier layer in high aspect ratio TSVs. The adhesion strength of the Co-W-B layer increased with increasing particle density of the Pd-NPs. These results indicate that the process with Pd-NPs catalyst is a promising method for the formation of a thin barrier layer in high aspect ratio TSVs at low temperatures.(c) 2012 Elsevier Ltd. All rights reserved.

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  • Origin of visible photoluminescence from arrays of vertically arranged Si-nanopillars decorated with Si-nanocrystals

    A. S. Kuznetsov, T. Shimizu, S. N. Kuznetsov, A. V. Klekachev, S. Shingubara, J. Vanacken, V. V. Moshchalkov

    NANOTECHNOLOGY   23 ( 47 )   2012年11月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)   出版者・発行元:IOP PUBLISHING LTD  

    Arrays of vertically aligned Si-nanopillars, with average diameters of 100 nm and 5 mu m length, have been prepared by wet chemical etching of crystalline silicon in a special manner. Samples with smooth-and porous-walled nanopillars have been studied. In the case of the latter, Si-nanocrystals, passivated with SiOx, decorating the surface of the nanopillars are identified by the means of TEM and FTIR. When excited by UV-blue light, the porous-walled Si-nanopillars are found to have a strong broad visible emission band around 1.8 eV with a nearly perfect Gaussian shape, mu s luminescence lifetimes, minor emission polarization and a non-monotonic temperature dependence of luminescence. The Si-nanocrystal surface is found to be responsible for the luminescence. The red-shift of the emission maximum and the luminescence quenching induced by oxidation in UV-ozone confirm this assumption. A model of luminescence involving UV photon absorption by Si-nanocrystals with subsequent exciton radiative recombination on defect sites in SiOx covering Si-nanocrystals has been proposed. Possible applications of the nanopillar arrays are discussed.

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  • AgNO3-Dependent Morphological Change of Si Nanostructures Prepared by Single-Step Metal Assisted Etching Method

    Tomohiro Shimizu, Takuya Yamaguchi, Fumihiro Inoue, Mitsuru Inada, Shoso Shingubara

    JAPANESE JOURNAL OF APPLIED PHYSICS   51 ( 11 )   2012年11月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)   出版者・発行元:IOP PUBLISHING LTD  

    The morphological changes of a nanostructured Si surface prepared by metal assisted etching were investigated. We used a mixture of silver nitrate (AgNO3) and hydrofluoric acid (HF) as an electroless plating bath of Ag, as well as an etching solution of Si. With a change in silver ion concentration in the etching solution, three types of etched Si nanostructures were observed: "nanowire", "porous wall", and "polished". We developed a phase diagram of the morphology of the etched Si surface. With increasing concentration of AgNO3 in the etching solution, the surface morphology of etched Si changes from nanowire to porous wall, and finally, polished for regardless of Si resistivity. (C) 2012 The Japan Society of Applied Physics

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  • Resistive switching characteristics of NiO/Ni nanostructure

    Shintaro Otsuka, Saeko Furuya, Ryota Takeda, Tomohiro Shimizu, Shoso Shingubara, Tadataka Watanabe, Yoshiki Takano, Kouichi Takase

    MICROELECTRONIC ENGINEERING   98   367 - 370   2012年10月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)   出版者・発行元:ELSEVIER SCIENCE BV  

    We have studied variation of switching voltage of resistive random access memory (ReRAM). Basically, the switching voltage at every switching has a different value because there are many conduction paths, which are randomly chosen at every switching with different conductivity in an oxide insulator between top and bottom electrodes. Limitation of the number of conductive paths is expected to lead the suppression of the variation of switching voltage. In this study, Ni nanorods buried into the nanoholes of an anodic aluminum oxide (MO) film have been fabricated to restrict the formation of many filaments and the switching behaviors of the In/NiO/Ni nanorods has been investigated. (C) 2012 Elsevier B.V. All rights reserved.

    DOI: 10.1016/j.mee.2012.07.035

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  • Fabrication of an array of Ni/NiO nanowire-ReRAM using AAO template on Si

    Tomohiro Shimizu, Yuzuru Sumita, Fumihiro Inoue, Tetsuji Minokuchi, Shoso Shingubara, Shintaro Otsuka, Koichi Takase

    e-Journal of Surface Science and Nanotechnology   10   476 - 479   2012年9月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)  

    The resistive switching random access memory (ReRAM) device using Ni/NiO nanowire as a building block was demonstrated
    this is prepared by a combination of top-down and bottom-up techniques. The Ni nanowire arrays on Si substrates were prepared by electroplating of Ni into the anodic aluminum oxide (AAO) template, and the surface of the nanowires were oxidized by O 2 plasma treatment at room temperature. We observed an improvement of stability of the switching properties in the nanowire device compared with the device using nickel oxide thin film. © 2012 The Surface Science Society of Japan.

    DOI: 10.1380/ejssnt.2012.476

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  • Additional Electrochemical Treatment Effects on the Switching Characteristics of Anodic Porous Alumina Resistive Switching Memory

    Shintaro Otsuka, Ryouta Takeda, Saeko Furuya, Tomohiro Shimizu, Shouso Shingubara, Nobuyuki Iwata, Tadataka Watanabe, Yoshiki Takano, Kouichi Takase

    JAPANESE JOURNAL OF APPLIED PHYSICS   51 ( 6 )   2012年6月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)   出版者・発行元:IOP PUBLISHING LTD  

    We have investigated the current-voltage characteristics of a resistive switching memory (ReRAM), especially the reproducibility of the switching voltage between an insulating state and a metallic state. The poor reproducibility hinders the practical use of this memory. According to a filament model, the variation of the switching voltage may be understood in terms of the random choice of filaments with different conductivities and lengths at each switching. A limitation of the number of conductive paths is expected to lead to the suppression of the variation of switching voltage. In this study, two strategies for the limitation have been proposed using an anodic porous alumina (APA). The first is the reduction of the number of conductive paths by restriction of the contact area between the top electrodes and the insulator. The second is the lowering of the resistivity of the insulator, which makes it possible to grow filaments with the same characteristics by electrochemical treatments using a pulse-electroplating technique. (C) 2012 The Japan Society of Applied Physics

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  • Evaluation of morphology and crystal structure of Si nanowires prepared by singlestep metal assisted etching

    Takuya Yamaguchi, Tomohiro Shimizu, Fumihiro Inoue, Chounge Wang, Mitsuru Inada, Tadashi Saitoh, Shoso Shingubara

    IMFEDK 2012 - 2012 International Meeting for Future of Electron Devices, Kansai   1439. AA03-02   84 - 85   2012年

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    記述言語:英語   掲載種別:研究論文(国際会議プロシーディングス)  

    The macro and micro morphology, and the crystal structure of Si nanowires prepared by singlestep catalytic metal assisted etching were investigated. Here, we prepared the Si nanowires by metal assisted etching with electroless-deposited Ag catalyst on Si (100) substrate. We used mixture of silver nitrite and hydrofluoric acid as a plating bath of Ag, as well as etching solution of Si. The morphology and crystalline structure of the nanowires as a function of concentration of silver nitrite in etching bath were investigated by SEM and cross-sectional TEM observations. With increasing concentration of the silver nitrite in the etching solution, the surface of nanowires tends to be porous structure with very fine pores of a few nm (porous Si nanowire). When concentration of silver nitrite is low, single crystal Si nanowires with a smooth surface without pores were observed. The porous Si nanowires consisted of the nano scaled crystals and partially amorphous Si nears its surface. © 2012 IEEE.

    DOI: 10.1109/IMFEDK.2012.6218593

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  • All-wet Cu-filled TSV Process Using Electroless Co-alloy Barrier and Cu Seed

    Fumihiro Inoue, Tomohiro Shimizu, Hiroshi Miyake, Ryohei Arima, Shoso Shingubara, Kansai University

    2012 IEEE 62ND ELECTRONIC COMPONENTS AND TECHNOLOGY CONFERENCE (ECTC)   810 - 815   2012年

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    記述言語:英語   掲載種別:研究論文(国際会議プロシーディングス)   出版者・発行元:IEEE  

    We demonstrated fabrication of Cu-TSV using all-wet process, which has a high potential to apply for the via-last Cu-TSV process. A Co-W alloy diffusion barrier layer was formed on SiO2 layer by electroless plating at 60 degrees C with Pd nanoparticle catalyst. The barrier layer was thin and continuous throughout a 2 phi x 24 mu m TSV and its adhesion strength on SiO2 was as high as that of PVD-Ta. The Co-W alloy layer has undergone an interdiffusion test, which showed a high resistance against Cu diffusion into SiO2 layer. Then, seed layer was formed by electroless Cu deposition on the Co-W alloy layer through displacement reaction. These results reveal a feasibility of all-wet fabrication in a high aspect ratio TSV process.

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  • Fabrication of an ordered anodic aluminum oxide pore arrays with an interpore distance smaller than the nano-indentation pitch formed by ion beam etching

    Chonge Wang, Yasuharu Ishida, Ken-Ichi Saitoh, Tomohiro Shimizu, Shoso Shingubara, Shukichi Tanaka

    IMFEDK 2012 - 2012 International Meeting for Future of Electron Devices, Kansai   1, 1-5   122 - 123   2012年

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    記述言語:英語   掲載種別:研究論文(国際会議プロシーディングス)  

    We investigated a method for preparation of self-ordering nanopore arrays with the interpore distance of 60nm by guided self-organization of anodic aluminum oxide (AAO) with a pre-patterned ordered array of indentations of Al film. An ordered triangular array of 100 nm-pitch indentations was formed on Al film by ion beam etching (IBE) with the EB resist mask, and then it was used as a guide for formation of AAO pore. We found it was possible to reduce an interpore distance of AAO to 1/√3 of the pitch of the indentation by the choice of appropriate IBE parameters and anodization voltage. © 2012 IEEE.

    DOI: 10.1109/IMFEDK.2012.6218612

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  • Cu2ZnSnS4 thin films and nanowires prepared by different single-step electrodeposition method in quaternary electrolyte

    Minsung Jeon, Tomohiro Shimizu, Shoso Shingubara

    MATERIALS LETTERS   65 ( 15-16 )   2364 - 2367   2011年8月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)   出版者・発行元:ELSEVIER SCIENCE BV  

    We investigated the effect of single-step electrodeposition methods for the fabrication of CZTS thin films as solar cell absorber layer. For deposition of CZTS thin films, a potentiostatic method and a pulsed potential electrodeposition method were examined. Near stoichiometric CZTS thin films were prepared by potentiostatic deposition method. On the other hands, the samples deposited by pulsed potential method showed wire-like CZTS nanostructures. The nanowires were composed of the Cu and S element mainly and included Zn and Sn microelements. From these results, we realized that the electrodeposition methods strongly affect the structural and compositional characteristics of as-deposited CZTS thin films. (C) 2011 Elsevier B.V. All rights reserved.

    DOI: 10.1016/j.matlet.2011.05.003

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  • Formation of electroless barrier and seed layers in a high aspect ratio through-Si vias using Au nanoparticle catalyst for all-wet Cu filling technology

    Fumihiro Inoue, Tomohiro Shimizu, Takumi Yokoyama, Hiroshi Miyake, Kazuo Kondo, Takeyasu Saito, Taro Hayashi, Shukichi Tanaka, Toshifumi Terui, Shoso Shingubara

    ELECTROCHIMICA ACTA   56 ( 17 )   6245 - 6250   2011年7月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)   出版者・発行元:PERGAMON-ELSEVIER SCIENCE LTD  

    An all-wet process was achieved using electroless deposition of barrier and Cu seed layers for fabrication of a high aspect ratio through-Si via (TSV). Formation of a thin barrier metal layer of Ni-B, Co-B and Co-W-B is possible using a Au nanoparticle (AuNP) catalyst, which is densely adsorbed on the SiO(2) of the TSV sidewall. A silane coupling agent of 3-aminopropyl-triethoxysilane is effective for enhancement of the density of adsorption for AuNP. A conformal electroless Cu layer is deposited on the barrier layer by displacement plating without a catalyst. The adhesion strength between the electroless barrier layer and the SiO(2) substrate is increased by annealing at 300 degrees C. These results strongly suggest that an all-wet process for the formation of Cu-filled TSV with a high aspect ratio is practically possible. (C) 2011 Elsevier Ltd. All rights reserved.

    DOI: 10.1016/j.electacta.2011.02.078

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  • Preparation of Ultrahigh-Density Magnetic Nanowire Arrays beyond 1 Terabit/Inch(2) on Si Substrate Using Anodic Aluminum Oxide Template

    Tomohiro Shimizu, Kazumo Aoki, Yoshinori Tanaka, Toshifumi Terui, Shoso Shingubara

    JAPANESE JOURNAL OF APPLIED PHYSICS   50 ( 6 )   2011年6月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)   出版者・発行元:JAPAN SOC APPLIED PHYSICS  

    Ultrahigh-density Co nanowire arrays were fabricated by the combined use of the anodic aluminum oxide (AAO) template formed on a Si substrate and pulse DC electrodeposition. The AAO templates were prepared with the anodic voltages from 3 to 40 V, whose diameters were from 15 to 40 nm. Using the AAO template with an anodic voltage less than 3 V, the wire density exceeded 2.88 Tbit/in.(2). The magnetic property of the nanowire arrays indicated a strong perpendicular magnetic anisotropy, and we observed the tendency of increase in coercivity with decreasing nanowire diameter. (C) 2011 The Japan Society of Applied Physics

    DOI: 10.1143/JJAP.50.06GE01

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  • Large Magnetoresistance Switching Phenomena in Nanoconduction Path Formed with Dielectric Breakdown of SiO2 Multilayered with Ferromagnetic Film

    Yuichi Shiotani, Kohei Shimomura, Tomohiro Shimizu, Shoso Shingubara

    JAPANESE JOURNAL OF APPLIED PHYSICS   50 ( 6 )   2011年6月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)   出版者・発行元:JAPAN SOC APPLIED PHYSICS  

    A large magnetoresistance exceeding 290% at room temperature was observed in a nanoconduction path (NCP) formed by dielectric breakdown of an SiO2 layer in contact with a ferromagnetic layer. Switching of the resistance between a low-resistance state (LRS) and a high-resistance state (HRS) occurred at magnetic fields of 0.2-0.6 T. The current-voltage characteristic of HRS showed a clear tunneling behavior, while that of LRS showed a weak nonlinearity. A set-up process with some amount of current stress was necessary to observe magnetoresistance switching. It is suggested that a nanogap is formed in a ferromagnetic NCP as a result of electromigration during the set-up process. The detailed mechanism has not yet been understood, however, magnetoresistance switching seems to be caused by a reproducible change of the nanogap distance concomitant with a switching of the magnetization of a ferromagnetic NCP. (C) 2011 The Japan Society of Applied Physics

    DOI: 10.1143/JJAP.50.06GG15

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  • Formation and Evaluation of Electroless-Plated Barrier Films for High-Aspect-Ratio Through-Si Vias

    Hiroshi Miyake, Fumihiro Inoue, Takumi Yokoyama, Tomohiro Shimizu, Shukichi Tanaka, Toshifumi Terui, Shoso Shingubara

    JAPANESE JOURNAL OF APPLIED PHYSICS   50 ( 5 )   2011年5月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)   出版者・発行元:JAPAN SOC APPLIED PHYSICS  

    The formation of a diffusion barrier layer in a through-Si via (TSV) has been studied with a combination of nanoparticle catalyst and electroless plating (ELP). We used Au-nanoparticles (Au-NPs) or Pd-nanoparticles (Pd-NPs) as catalysts for ELP of Ni- and Co-alloy barrier layers. We studied deposition of Ni-B and Co-B films in high-aspect-ratio (AR) TSV. Then, we succeeded in controlling the deposition profile of Ni- B in a high-AR TSV by the addition of bis(3-sulfopropyl)-disulfide (SPS). SPS turned out to be an inhibitor of electroless plating of Ni-B. On the other hand, the Co-B film was deposited conformally without additive. The electrical resistivity of Cu after annealing Cu/barrier stacked structure suggests that Co-B has better thermal stability than Ni-B. (C) 2011 The Japan Society of Applied Physics

    DOI: 10.1143/JJAP.50.05ED01

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  • Control of crystal orientation of epitaxial Si nanowires on Si substrate using AAO template

    Tomohiro Shimizu, Qi Wang, Chonge Wang, Fumihiro Inoue, Makoto Koto, Minsung Jeon, Shoso Shingubara

    Materials Research Society Symposium Proceedings   1350   59 - 62   2011年

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    記述言語:英語   掲載種別:研究論文(国際会議プロシーディングス)  

    Control of crystal orientation of vertically grown epitaxial Si (111) and (110) nanowire arrays on Si substrate has been demonstrated using a combination of an anodic aluminum oxide (AAO) template and vapor - liquid - solid (VLS) growth method. The crystal orientation of the nanowire was investigated by transmission electron microscopy. A growth direction of the nanowire arrays was guided perpendicular to the surface of the substrate by the AAO template, and the crystal orientation of the nanowire arrays was selected using the single crystal Si substrate properly cut in desired orientation. © 2011 Materials Research Society.

    DOI: 10.1557/opl.2011.1131

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  • Oxidation Rate Effect on the Direction of Metal-Assisted Chemical and Electrochemical Etching of Silicon

    Zhipeng Huang, Tomohiro Shimizu, Stephan Senz, Zhang Zhang, Nadine Geyer, Ulrich Goesele

    JOURNAL OF PHYSICAL CHEMISTRY C   114 ( 24 )   10683 - 10690   2010年6月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)   出版者・発行元:AMER CHEMICAL SOC  

    Assisted by noble metal particles, non-(100) Si substrates were etched in solutions with different oxidant concentrations at different temperatures. The etching directions of (110) and (111) Si substrates are found to be influenced by the concentration of oxidant in etching solutions. In solutions with low oxidant concentration, the etching proceeds along the crystallographically preferred (100) directions, whereas the etching occurs along the vertical direction relative to the surface of the substrate in solutions with high oxidant concentration. These phenomena are found for both and p-type substrates as well as in experiments with different oxidants. The experiments on metal-assisted chemical etching are complemented by additional experiments on metal-assisted electrochemical etching of (111) Si substrates with different current densities. As a function of current density, a change of etching directions is observed. This shows that the change of the etching directions is mainly driven by the oxidation rate. On the basis of these phenomena, we have demonstrated fabrication of Si nanopores with modulated orientations by periodically etching a (111) substrate in solutions of low and high oxidant concentrations.

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  • Synthesis of silicon nanotubes with cobalt silicide ends using anodized aluminum oxide template

    Zhang Zhang, Lifeng Liu, Tomohiro Shimizu, Stephan Senz, Ulrich Goesele

    NANOTECHNOLOGY   21 ( 5 )   2010年2月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)   出版者・発行元:IOP PUBLISHING LTD  

    Silicon nanotubes (SiNTs) are compatible with Si-based semiconductor technology. In particular, the small diameters and controllable structure of such nanotubes are remaining challenges. Here we describe a method to fabricate SiNTs intrinsically connected with cobalt silicide ends based on highly ordered anodic aluminum oxide (AAO) templates. Size and growth direction of the SiNTs can be well controlled via the templates. The growth of SiNTs is catalyzed by the Co nanoparticles reduced on the pore walls of the AAO after annealing, with a controllable thickness at a given growth temperature and time. Simultaneously, cobalt silicide forms on the bottom side of the SiNTs.

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  • Bottom-Imprint Method for VSS Growth of Epitaxial Silicon Nanowire Arrays with an Aluminium Catalyst

    Zhang Zhang, Tomohiro Shimizu, Lijun Chen, Stephan Senz, Ulrich Goesele

    ADVANCED MATERIALS   21 ( 46 )   4701 - +   2009年12月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)   出版者・発行元:WILEY-V C H VERLAG GMBH  

    A bottom-imprint method to fabricate high-quality Si [100] nanowire arrays is described (see figure). This new approach combines the functions of a highly ordered anodic aluminum oxide (AAO) template that acts as both a stamp and a template. Vertically aligned, Al-catalyzed Si nanowire (NW) arrays are grown epitaxially on the Si substrate with a narrow size distribution.

    DOI: 10.1002/adma.200900995

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  • Ordered Arrays of Vertically Aligned [110] Silicon Nanowires by Suppressing the Crystallographically Preferred Etching Directions

    Zhipeng Huang, Tomohiro Shimizu, Stephan Senz, Zhang Zhang, Xuanxiong Zhang, Woo Lee, Nadine Geyer, Ulrich Goesele

    NANO LETTERS   9 ( 7 )   2519 - 2525   2009年7月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)   出版者・発行元:AMER CHEMICAL SOC  

    The metal-assisted etching direction of Si(110) substrates was found to be dependent upon the morphology of the deposited metal catalyst. The etching direction of a Si(110) substrate was found to be one of the two crystallographically preferred &lt; 100 &gt; directions in the case of isolated metal particles or a small area metal mesh with nanoholes. In contrast, the etching proceeded in the vertical [(1) over bar(1) over bar0] direction, when the lateral size of the catalytic metal mesh was sufficiently large. Therefore, the direction of etching and the resulting nanostructures obtained by metal-assisted etching can be easily controlled by an: appropriate choice of the morphology of the deposited metal catalyst. On the basis of this finding, a generic method was developed for the fabrication of wafer-scale vertically aligned arrays of epitaxial [110] Si nanowires on a Si(110) substrate. The method utilized a thin metal film with an extended array of pores as an etching catalyst based on an ultrathin porous anodic alumina mask, while a prepatterning of the substrate prior to the metal depostion is not necessary. The diameter of Si nanowires can be easily controlled by-a combination of the pore diameter of the porous alumina film and varying the thickness of the deposited metal film.

    DOI: 10.1021/nl803558n

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  • Ordered High-Density Si [100] Nanowire Arrays Epitaxially Grown by Bottom Imprint Method

    Zhang Zhang, Tomohiro Shimizu, Stephan Senz, Ulrich Goesele

    ADVANCED MATERIALS   21 ( 27 )   2824 - +   2009年7月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)   出版者・発行元:WILEY-V C H VERLAG GMBH  

    A novel bottom imprint method to fabricate high-quality Si [100] nanowire arrays is demonstrated. This new approach combines the functions of a high-ordering AAO template as a stamp and template simultaneously. By the protective polymer layer in the hot imprint, the vertical 40 nm Si nanowire arrays grow epitaxially on the Si substrate with a narrow size distribution

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  • Vertical Epitaxial Wire-on-Wire Growth of Ge/Si on Si(100) Substrate

    Tomohiro Shimizu, Zhang Zhang, Shoso Shingubara, Stephan Senz, Ulrich Goesele

    NANO LETTERS   9 ( 4 )   1523 - 1526   2009年4月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)   出版者・発行元:AMER CHEMICAL SOC  

    Vertically aligned epitaxial Ge/Si heterostructure nanowire arrays on Si(100) substrates were prepared by a two-step chemical vapor deposition method in anodic aluminum oxide templates. n-Butylgermane vapor was employed as new safer precursor for Ge nanowire growth instead of germane. First a Si nanowire was grown by the vapor liquid solid growth mechanism using Au as catalyst and silane. The second step was the growth of Ge nanowires on top of the Si nanowires. The method presented will allow preparing epitaxially grown vertical heterostructure nanowires consisting of multiple materials on an arbitrary substrate avoiding undesired lateral growth.

    DOI: 10.1021/nl8035756

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  • Extended arrays of vertically aligned sub-10 nm diameter [100] Si nanowires by metal-assisted chemical etching

    Zhipeng Huang, Xuanxiong Zhang, Manfred Reiche, Lifeng Liu, Woo Lee, Tomohiro Shimizu, Stephan Senz, Ulrich Goesele

    NANO LETTERS   8 ( 9 )   3046 - 3051   2008年9月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)   出版者・発行元:AMER CHEMICAL SOC  

    Large-area high density silicon nanowire (SiNW) arrays were fabricated by metal-assisted chemical etching of silicon, utilizing anodic aluminum oxide (AAO) as a patterning mask of a thin metallic film on a Si (100) substrate. Both the diameter of the pores in the AAO mask and the thickness of the metal film affected the diameter of SiNWs. The diameter of the SiNWs decreased with an increase of thickness of the metal film. Large-area SiNWs with average diameters of 20 nm down to 8 nm and wire densities as high as 10(10) wires/cm(2) were accomplished. These SiNWs were single crystalline and vertically aligned to the (100) substrate. It was revealed by transmission electron microscopy that the SiNWs were of high crystalline quality and showed a smooth surface.

    DOI: 10.1021/nl802324y

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  • Synthesis of epitaxial Si(100) nanowires on Si(100) substrate using vapor-liquid-solid growth in anodic aluminum oxide nanopore arrays

    T. Shimizu, S. Senz, S. Shingubara, U. Goesele

    APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING   87 ( 4 )   607 - 610   2007年6月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)   出版者・発行元:SPRINGER  

    The synthesis of epitaxial Si nanowires with growth direction parallel to Si [100] on Si(100) substrate was demonstrated using a combination of anodic aluminum oxide (AAO) template, catalytic gold film sandwiched between the template and the Si(100) substrate and vapor-liquid-solid growth using SiH4 as the Si source. After growing out from the AAO nanopores, most Si nanowires changed their diameter and growth direction into larger diameter and (111) direction.

    DOI: 10.1007/s00339-007-3984-y

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  • Synthesis of vertical high-density epitaxial Si(100) nanowire arrays on a Si(100) substrate using an anodic aluminum oxide template

    Tomohiro Shimizu, Tian Xie, Jo Nishikawa, Shoso Shingubara, Stephan Senz, Ulrich Goesele

    ADVANCED MATERIALS   19 ( 7 )   917 - +   2007年4月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)   出版者・発行元:WILEY-V C H VERLAG GMBH  

    Growth of vertical epitaxial Si(100) nanowires on Si(100) substrates is demonstrated (see figure) using a combination of an anodic aluminum oxide template, catalytic An particles embedded in nanopores directly on the Si substrate by using electroless deposition, and vapor-liquid-solid growth using SiH4. HF acid treatment of the porous alumina template is important to realize a direct contact between deposited An in the AAO nanopores and the Si substrate.

    DOI: 10.1002/adma.200700153

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  • Homoepitaxial growth of vertical Si nanowires on Si (100) substrate using Anodic Aluminum Oxide template 査読

    SHIMIZU Tomohiro, XIE T, SCHMIDT V, NISHIKAWA Jo, SHINGUBARA Shoso, SENZ S, GOESELE U

    Materials Research Society   1058E, JJ03-01   2007年

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  • Epitaxial growth of Cu nanodot arrays using an AAO template on a Si substrate

    T Shimizu, M Nagayanagi, T Ishida, O Sakata, T Oku, H Sakaue, T Takahagi, S Shingubara

    ELECTROCHEMICAL AND SOLID STATE LETTERS   9 ( 4 )   J13 - J16   2006年

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    記述言語:英語   掲載種別:研究論文(学術雑誌)   出版者・発行元:ELECTROCHEMICAL SOC INC  

    We established a method to clean the Si surface that exists at the bottom of anodic aluminum oxide (AAO) nanoholes after removal of the amorphous barrier layer, and we succeeded in the preparation of epitaxial Cu dot arrays on the Si surface in the nanoholes. The Si surfaces at the AAO nanohole bottoms were cleaned with dilute hydrofluoric acid after annealing at 900 degrees C in Ar ambient, and we sputtered Cu on the AAO template to form Cu dot arrays. This method for preparing nanohole arrays on a single crystalline substrate enables growth of a variety of highly regular epitaxial nanodot/wire arrays. (c) 2006 The Electrochemical Society.

    DOI: 10.1149/1.2176891

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  • Fabrication of carbon nanotube and nanorod arrays using nanoporous templates

    SJ Huang, T Shimizu, H Sakaue, S Shingubara, T Takahagi

    JAPANESE JOURNAL OF APPLIED PHYSICS PART 1-REGULAR PAPERS BRIEF COMMUNICATIONS & REVIEW PAPERS   44 ( 7A )   5289 - 5291   2005年7月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)   出版者・発行元:JAPAN SOC APPLIED PHYSICS  

    A simple fabrication process is presented for highly-ordered, highly-oriented carbon nanotube and nanorod arrays by filling alumina nanohole templates with a carbon precursor, polyacrylonitrile (PAN). X-ray photoelectron spectra analysis indicates that PAN changes its chemical structure to sp(2) C-C structure after carbonization at 600 degrees C. Raman characterization of the resulting carbon nanostructure demonstrates a high quality graphite structure. The proposed method may be used to develop carbon nanostructure-based devices.

    DOI: 10.1143/JJAP.44.5289

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  • Aspect ratio dependence of hysteresis property of high density Co wire array buried in porous alumina template

    S Shingubara, K Morimoto, M Nagayanagi, T Shimizu, O Yaegashi, GR Wu, H Sakaue, T Takahagi, K Takase

    JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS   272   1598 - 1599   2004年5月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)   出版者・発行元:ELSEVIER SCIENCE BV  

    Co wire array with 50 nm intervals was formed by electrodeposition in porous alumina template that was formed on Si substrate. Coercive field of Co wire array under perpendicular magnetic field significantly increased when aspect ratio increased from 1.5 to 2.5. This behavior was well explained by the micromagnetic simulation when magnetic anisotropy axis was assumed to be parallel to the substrate. (C) 2003 Elsevier B.V. All rights reserved.

    DOI: 10.1016/j.jmmm.2003.12.320

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  • Formation of ultra-high-density ferromagnetic column arrays beyond 1 Tera/inch2 using porous alumina template 査読

    SHIMIZU Tomohiro, NAGAYANAGI Mamoru, FUJII Y, YAEGASHI O, WU G, SAKAUE H, TAKAHAGI T, SHINGUBARA Shoso

    Transaction of Magnetic society of Japan   4, 231-234   2004年

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  • Electronic structure of oxysulfide (LaO)CuS and (La1-xCaxO)Cu1-xNixS (x≦0.10) studied by photoemission and inverse-photoemission spectroscopies

    SATO H, NEGISHI H, WADA A, INO A, NEGISHI S, HIRAI C, NAMATAME H, TANIGUCHI M, TAKASE K, TAKAHASHI Y, SHIMIZU Tomohiro, TAKANO Y, SEKIZAWA K

    Physical Rev. B   68 ( 3 )   2003年7月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)  

    DOI: 10.1103/PhysRevB.68.035112

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  • Static and Dynamic transport study of -FeSi2 single crystals

    HARA Y, TAKASE K, SHIMIZU Tomohiro, OHNISHI A, SASAKI M

    Physica B   329   1113 - 1114   2003年5月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)  

    DOI: 10.1016/S0921-4526(02)02462-6

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  • Electrical resistivity and photoemission spectra of layered oxysulfide (La1-xCaxO)Cu1-xNixS 査読

    TAKASE Koichi, SHIMIZU Tomohiro, MAKIHARA K, SATO H, NEGISHI H, TAKAHASHI Y, TAKANO Y, SEKIZAWA K, KUROIWA Y, AOYAGI S, UTSUMI A, WADA A, INO A, NAMETAKE H, TANIGUCHI M

    Physica B   329-333, 898-899   2003年

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  • Electrical resistivity and photoluminescence spectrum of layered oxysulfide (LaO)CuS 査読

    TAKASE Koichi, KOYANO M, SHIMIZU Tomohiro, MAKIHARA K, TAKANO Y, SEKIZAWA K

    Solid state commn.   123, 531-534   2002年

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▼全件表示

MISC

  • Fabrication of ultra high density ferromagnetic column arrays by porous alumina template for magnetic recording media

    T. Shimizu, K. Morimoto, M. Nagayanagi, Y. Fujii, O. Yaegashi, G. R. Wu, H. Sakaue, T. Takahagi, S. Shingubara

    Digest of Papers - Microprocesses and Nanotechnology 2003 - 2003 International Microprocesses and Nanotechnology Conference, MNC 2003   62 - 63   2003年

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    記述言語:英語   出版者・発行元:Institute of Electrical and Electronics Engineers Inc.  

    In this paper, we succeeded in the fabrication of Co columns that had perpendicular anisotropy with density of 800 Gbit/inch/sup 2/. The proposed method for realizing the high-density magnetic recording media is suitable for obtaining perpendicular anisotropy, since the anisotropy can be controlled by changing the aspect ratio of the magnetic columns. For realizing ferromagnetic column array with higher recording density, filling of ferromagnetic materials in the porous alumina nanoholes formed at anodic voltages lower than 10 V is essential, and further study is in progress.

    DOI: 10.1109/IMNC.2003.1268519

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講演・口頭発表等

  • Formation and evaluation of Cu2ZnSnS4 films prepared by electroplating and sulfurization with CS2

    NISHIDA T, SHIMIZU T, TAKASE K, TANAKA S, ITO T, SHINGUBARA S

    2016年11月 

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    開催年月日: 2016年11月

    開催地:Singapore  

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  • Sensitized Mass Change Detection by Using Au Nanoporous Electrode for Biosensing

    TERASAWA H, ASAI N, SHIMIZU T, SHINGUBARA S, ITO T

    2016年11月 

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    開催年月日: 2016年11月

    開催地:Kyoto  

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  • Nano-porous Lattice Biosensor Using Anodic Aluminum Oxide Substrate

    Matsuda Y, ASAI N, SHIMIZU T, SHINGUBARA S, ITO T

    2016年11月 

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    開催年月日: 2016年11月

    開催地:Kyoto  

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  • Magnetic conductive filament formed in the ReRAM device with ferromagnetic electrode

    YOSHYIDA H, SHIMIZU T, ITO T, SHINGUBARA S

    2016年10月 

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    開催年月日: 2016年10月

    開催地:Hawaii, USA  

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  • Antibacterial Property of Si Nanopillar Array Fabricated Using Metal Assisted Etching; Mimic a Cicada Wing

    ITO T, NAKADE K, ASAI N, SHIMIZU T, SHINGUBARA S

    2016年10月 

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    開催年月日: 2016年10月

    開催地:Hawaii, USA  

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  • Fabricating a QCM Device with the Nanostructures Using the AAO Template

    ASAI N, ITO T, SHIMIZU T, SHINGUBARA S

    2016年10月 

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    開催年月日: 2016年10月

    開催地:Hawaii, USA  

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  • Electroless plating of diffusion barrier films on SiO2 and evaluation of film characteristics

    HIRATE A, MIYACHI Y, OHTA K, SHIMIZU T, ITO T, SHINGUBARA S

    2016年10月 

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    開催年月日: 2016年10月

    開催地:Hawaii, USA  

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  • Oxidation of CuSn alloy nano-tree and application for gas sensors

    KANEKO N, SHIMIZU T, ITO T, TADA Y, SHINGUBARA S

    2016年10月 

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    開催年月日: 2016年10月

    開催地:Hawaii, USA  

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  • Electrodeposited ZnO thin film on twin sensor QCM for sensing of ethanol at room temperature

    ITO T, FUJII Y, YMANISHI N, SHIMIZU T, SHINGUBARA S

    2016年9月 

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    開催年月日: 2016年9月

    開催地:Hungary  

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  • Antibacterial characteristics of Si nano-pillar array

    ITO T, NAKADE K, ASAI N, SHIMIZU T, SHINGUBARA S

    2016年9月 

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    開催年月日: 2016年9月

    開催地:Sendai, Japan  

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  • Formation of Si moth-eye structures using 2-step metal assisted chemical etching

    SHIMIZU T, TAKASE K, ITO T, SHINGUBARA S

    2016年7月 

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    開催年月日: 2016年7月

    開催地:Tessalonik, Greece  

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  • Fabrication of Vertical Cu2ZnSnS4/Mo/Si Nanocylinder Arrays Using a Patterned Si Nanowire Arrays Template

    WANG C, SHIMIZU T, SHINGUBARA S

    2016年6月 

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    開催年月日: 2016年6月

    開催地:Munich, Germany  

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  • Opto-electronic properties of Cu2ZnSnS4 films prepared using electroplating and CS2 sulfurization process

    SHIMIZU T, NISHIDA K, NISHIDA T, TAKASE K, WANG C, TANAKA S, SHINGUBARA S

    2016年6月 

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    開催年月日: 2016年6月

    開催地:Munich, Germany  

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  • Highly adhesive displacement plated Cu seed on CoWB barrier for all-wet TSV fill process

    SHINGUBARA S, OHTA K, INOUE F, ITO T, SHIMIZU T

    2016年3月 

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    開催年月日: 2016年3月

    開催地:Brussels, Belgium  

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  • Non-enzymatic detection of glucose using BaCuO2 thin layer

    ITO T, ASADA T, ASAI N, SHIMIZU T, SHINGUBARA S

    2016年3月 

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    開催年月日: 2016年3月

    開催地:Nagoya, Japan  

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  • Fabrication and optical property of metal nanowire arrays embedded in anodic porous alumina membrane

    TAKASE K, SHIMIZU T, SUGAWA K, SHINGUBARA S

    2015年11月 

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    開催年月日: 2015年11月

    開催地:Toyama, Japan  

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  • Switching and Magnetoresistance Characteristics Observed in the ReRAM Device with Ferromagnetic Electrodes

    YOSHYIDA H, ITO D, SHIMIZU T, ITO T, SHINGUBARA S

    2015年11月 

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    開催年月日: 2015年11月

    開催地:Toyama, Japan  

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  • Oxidation of CuSn alloy nanotree and application for gas sensors

    KANEKO N, SHIMIZU T, TADA Y, ITO T, SHINGUBARA S

    2015年11月 

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    開催年月日: 2015年11月

    開催地:Toyama, Japan  

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  • Highly adhesive displacement plated Cu seed layer for all-wet TSV fill process

    OHTA K, INOUE F, SHIMIZU T, SHINGUBARA S

    2015年10月 

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    開催年月日: 2015年10月

    開催地:Phonenics, USA  

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  • Resistance switching phenomenon associated with anisotropic magnetoresistance ofthe ReRAM device with ferromagnetic electrodes

    ITO D, YOSHIDA H, SHIMIZU T, SHINGUBARA S

    2015年10月 

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    開催年月日: 2015年10月

    開催地:Phonenics, USA  

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  • Fabrication of nanocone arrays by two step metal assisted chemical etching method

    TANAKA N, SHIMIZU T, TADA Y, HARA Y, NAKAMURA N, TANIUCHI J, TAKASE K, ITO T, SHINGUBARA S

    2015年9月 

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    開催年月日: 2015年9月

    開催地:Hague, Netherlands  

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  • All-wet TSV filling with highly adhesive displacement plated Cu seed layer

    OHTA K, INOUE F, SHIMIZU T, SHINGUBARA S

    2015年9月 

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    開催年月日: 2015年9月

    開催地:Sendai, Japan  

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  • Temperature dependence of magnetoresistance characteristics of the on-state of resistive random access memory with ferromagnetic electrode

    ITO D, HAMADA Y, OTSUKA S, SHIMIZU T, SHINGUBARA S

    2015年6月 

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    開催年月日: 2015年6月

    開催地:Kyoto, Japan  

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  • Effect of additive on the formation of CuSn Alloynano-trees formed with DC Electroplating

    SHINGUBARA S, SHIMIZU T, KANEKO N, TADA Y

    2015年5月 

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    開催年月日: 2015年5月

    開催地:Chicago, USA  

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  • CuSn合金ナノツリー構造体の電解めっき形成と評価

    夛田 芳広, 新宮原 正三, 清水 智弘, 岡 演之

    2014年電気化学会第81回大会  2014年3月 

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    開催年月日: 2014年3月

    開催地:大阪  

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  • Temperature Dependence of Resistance of Conductive Nano-filament Formed in Resistance Change Memory

    OTSUKA S, HAMADA Y, SHIMIZU T, SHINGUBARA S

    第61回応用物理学会春季学術講演会  2014年3月 

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    開催年月日: 2014年3月

    開催地:神奈川  

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  • 凝集構造を利用したSi ナノワイヤ配列の光学特性制御

    山口 卓也, 清水 智弘, 新宮原 正三

    第61回応用物理学会春季学術講演会  2014年3月 

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    開催年月日: 2014年3月

    開催地:神奈川  

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  • 自己集合ポリスチレン球とメタルアシストエッチングを用いた規則配列Siナノワイヤ作製と光学特性評価

    近藤 彰人, 山口 卓也, 王 崇娥, 原 康寛, 清水 智弘, 新宮原 正三

    2014年電気化学会第81回大会  2014年3月 

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    開催年月日: 2014年3月

    開催地:大阪  

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  • 窒素中性粒子ビームによるSi表面の窒化

    原 安寛, 清水 智弘, 新宮原 正三

    第61回応用物理学会春季学術講演会  2014年3月 

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    開催年月日: 2014年3月

    開催地:神奈川  

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  • Enhancement of light absorption using bunched Si nanowire arrays

    YAMAGUCHI T, SHIMIZU T, MOROSAWA Y, TAKASE K, SHINGUBARA S

    Material Research Society fall meeting 2013  2013年11月 

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    開催年月日: 2013年11月

    開催地:Boston, USA  

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  • Study on collective morphology dependence of optical reflectanceproperties for a high density array of silicon nanowires

    YAMAGUCHI T, SHIMIZU T, MOROSAWA Y, TAKASE K, SHINGUBARA S

    26th International Microprocesses and Nanotechinology Conference  2013年11月 

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    開催年月日: 2013年11月

    開催地:Sapporo  

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  • Fabrication of Cu2ZnSnS4 thin films by sulfurization of electrodeposited CuZn/CuSn precursor layers with CS2

    WANG C, SHIMIZU T, TANAKA S, KAWAKAMI A, KONDO A, TERUI T, TAKASE K, SHINGUBARA S

    23rd International Photovoltaic Science and Engineering Conference  2013年11月 

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    開催年月日: 2013年11月

    開催地:Taipei, Taiwan  

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  • Niナノワイヤを用いた抵抗変化型メモリの形成と評価

    京見 拓也, 大塚 慎太郎, 清水 智弘, 新宮原 正三

    第33回表面科学学術講演会  2013年11月 

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    開催年月日: 2013年11月

    開催地:茨城  

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  • Effect of confining filaments on the current – voltage characteristics of resistive change memory by using anodic porous alumina

    TANIMOTO Y, HAMADA Y, OTSUKA S, SHIMIZU T, SHINGUBARA S, WATANABE T, TAKANO Y, TAKASE K

    26th International Microprocesses and Nanotechinology Conference  2013年11月 

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    開催年月日: 2013年11月

    開催地:Sapporo  

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  • Study on conductive filaments formed in ReRAM devices through temperature dependence of electrical transport properties

    HAMADA Y, ITO D, OTSUKA S, SHIMIZU T, SHINGUBARA S

    26th International Microprocesses and Nanotechinology Conference  2013年11月 

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    開催年月日: 2013年11月

    開催地:Sapporo  

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  • Temperature Dependence of Resistance of Conductive Nano-filament Formed in Ni/NiOx/Pt ReRAM

    OTSUKA S, HAMADA Y, SHIMIZU T, SHINGUBARA S

    ADMETA Plus 2013: Asiasn Session  2013年10月 

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    開催年月日: 2013年10月

    開催地:Tokyo  

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  • Highly conformal and adhesive electroless barrier and Cu seed formationusing nanoparticle catalyst for realizing a high aspect ratio Cu-filled TSV

    NISHIZAWA S, ARIMA R, INOUE F, SHIMIZU T, SHINGUBARA S

    IEEE 3DIC-2013  2013年10月 

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    開催年月日: 2013年10月

    開催地:Sanfrancisco, USA  

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  • 金属酸化膜中に形成された導電性フィラメントの抵抗温度依存性

    濱田 佳典, 大塚 慎太郎, 伊藤 大介, 清水 智弘, 新宮原 正三

    第74回応用物理学会秋季学術講演会  2013年9月 

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    開催年月日: 2013年9月

    開催地:京都  

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  • 高密着性無電解めっきバリア膜の検討とTSVプロセスへの応用

    西澤 正一郎, 井上 史大, 清水 智弘, 新宮原 正三

    MES 2013  2013年9月 

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    開催年月日: 2013年9月

    開催地:大阪  

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  • Fabrication and absorption properties of ordered Si nanowire arrays using porous aluminum mask

    SHIMIZU T, YAMAGUCHI T, TAKASE K, SHINGUBARA S

    International Porous Powder Materials 2013  2013年9月 

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    開催年月日: 2013年9月

    開催地:Izmir, Turkey  

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  • メタルアシストエッチングと陽極酸化アルミナを用いた規則配列Si ナノワイヤの形成と反射率特性評価

    山口 卓也, 清水 智弘, 新宮原 正三

    2013年精密工学会  2013年9月 

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    開催年月日: 2013年9月

    開催地:大阪  

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  • S i ナノワイヤ配列の光学特性の凝集度による相違

    山口 卓也, 清水 智弘, 高瀬 浩一, 諸沢 泰裕, 中原 住雄, 新宮原 正三

    第74回応用物理学会秋季学術講演会  2013年9月 

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    開催年月日: 2013年9月

    開催地:京都  

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  • Fabrication of Cu2ZnSnS4 thin films by sulfurization of electrodeposited CuZn/CuSn precursor layers with CS2

    WANG C, KONDO A, TERUI T, TANAKA S, TAKASE T, SHIMIZU T, SHINGBARA S

    第74回応用物理学会秋季学術講演会  2013年9月 

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    開催年月日: 2013年9月

    開催地:京都  

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  • Enhancement of light absorption using bunched Si nanowire arrays

    HAMADA Y, KATO T, OTSUKA S, SHIMIZU T, SHINGUBARA S

    The 2013 International Meeting for Future of Electron Device, Kansai  2013年6月 

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    開催年月日: 2013年6月

    開催地:Osaka  

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  • 自己組織テンプレートとメタルアシストエッチング法を用いた規則配列Siナノワイヤ形成と評価

    山口 卓也, 清水 智弘, 夛田 芳広, 新宮原 正三

    第60回応用物理学会春季学術講演会  2013年3月 

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    開催年月日: 2013年3月

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  • 電気化学処理を施した硫酸陽極酸化アルミナを用いた抵抗変化素子の電流電圧特性

    谷本 優輔, 古屋 沙絵子, 大塚 慎太郎, 清水 智弘, 新宮原 正三, 渡辺 忠孝, 高野 良紀, 高瀬 浩一

    第60回応用物理学会春季学術講演会  2013年3月 

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    開催年月日: 2013年3月

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  • 高アスペクト比TSVへの無電解めっき皮膜形成に向けたPdナノ粒子触媒吸着

    井上 史大, 清水 智弘, 三宅 浩志, 有馬 良平, 伊藤 俊彦, 關 洋文, 篠崎 夕子, 山本 智彦, 新宮原 正三

    第60回応用物理学会春季学術講演会  2013年3月 

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    開催年月日: 2013年3月

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  • VLS法によるナノワイヤ成長 拡散抑制層追加による成長の改善

    古藤 誠, 清水 智弘, 新宮原 正三

    第60回応用物理学会春季学術講演会  2013年3月 

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    開催年月日: 2013年3月

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  • ガスセンサ応用に向けた銅錫酸化物ナノツリー構造の形成と評価

    夛田 芳広, 田中 良典, 清水 智弘, 新宮原 正三

    第60回応用物理学会春季学術講演会  2013年3月 

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    開催年月日: 2013年3月

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  • Fabrication of Cu2ZnSnS4 nanowire arrays using electroplating with nanohole template

    WANG C, TANAKA Y, TERUI T, TANAKA S, SHIMIZU T, SHINGUBARA S

    PCSEC-22  2012年11月 

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    開催年月日: 2012年11月

    開催地:HANGZHOU. CHINA  

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  • Electric Conduction Mechanism of Resistive Switching Memory using Anodic Porous Alumina

    OTSUKA S, SHIMIZU T, SHINGUBARA S, IWATA N, WATANABE T, TAKANO Y, TAKASE K

    PRiME 2012  2012年10月 

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    開催年月日: 2012年10月

    開催地:Honolulu, USA  

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  • Large Resistive Switching Phenomenon Induced by Magnetic Field in Nano Conduction Path

    KATO T, SHIMIZU T, OTSUKA S, KYOMI T, SHINGUBARA S

    PRiME 2012  2012年10月 

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    開催年月日: 2012年10月

    開催地:Honolulu, USA  

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  • Control of Adhesion Strength and TSV Filling Morphology of Electroless Barrier Layer

    ARIMA R, INOUE F, MIYAKE H, SHIMIZU T, SHINGUBARA S

    PRiME 2012  2012年10月 

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    開催年月日: 2012年10月

    開催地:Honolulu, USA  

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  • Control of the Morphology of Si Nanostructure Using Single-Step Metal Assisted Etching

    YAMAGUCHI T, SHIMIZU T, INOUE F, WANG C, OTSUKA S, TADA Y, INADA M, SHINGUBARA S

    PRiME 2012  2012年10月 

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    開催年月日: 2012年10月

    開催地:Honolulu, USA  

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  • Temperature dependence of resistance of conductive filament formed by dielectric breakdown

    OTSUKA S, KATO T, KYOMI T, HAMADA Y, TADA Y, SHIMIZU T, SHINGUBARA S

    MNC 2012  2012年10月 

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    開催年月日: 2012年10月

    開催地:KOBE, JAPAN  

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  • Fabrication of nanostructured Cu2ZnSnS4 using electrodepostion with AAO template

    TANAKA Y, WANG C, KONDOU A, SHIMIZU T, SHINGUBARA S

    MNC 2012  2012年10月 

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    開催年月日: 2012年10月

    開催地:KOBE, JAPAN  

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  • Control of crystal orientation and diameter of Si nanowire using anodic aluminum oxide template

    SHIMIZU T, SHINGUBARA S

    MNC 2012  2012年10月 

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    開催年月日: 2012年10月

    開催地:KOBE, JAPAN  

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  • Anodic condition dependence of current-voltage characteristic of resistive change memory using anodic porous alumina

    FURUYA S, OTUKA S, SHIMIZU T, SHINGUBARA S, WATANABE T, TAKANO Y, TAKASE K

    MNC 2012  2012年10月 

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    開催年月日: 2012年10月

    開催地:KOBE, JAPAN  

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  • 金属触媒とポーラスアルミナを用いた垂直シリコンナノワイヤ配列の形成

    清水 智弘, 夛田 芳裕, 山口 卓也, 新宮原 正三

    第4回マイクロ・ナノ工学シンポジウム  2012年10月 

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    開催年月日: 2012年10月

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  • Improvement of Adhesion Strength of Electroless Barrier Layer on SiO2 and Control of Deposition Profile in a High Aspect Ratio TSV

    NISHIZAWA S, INOUE F, ARIMA R, SHIMIZU T, SHINGUBARA S

    ADMETA 2012  2012年10月 

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    開催年月日: 2012年10月

    開催地:TOKYO, JAPAN  

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  • abrication of vertical Cu2ZnSnS4 nanowire arrays using anodic aluminum oxide templates

    王 崇娥, 田中 良典, 照井 通文, 田中 秀吉, 清水 智弘, 新宮原 正三

    第73回応用物理学会秋季学術講演会  2012年9月 

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    開催年月日: 2012年9月

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  • SiO2上の無電解バリアメタル膜の密着性向上の検討

    西沢 正一郎, 井上 史大, 有馬 良平, 清水智弘, 新宮原 正三

    第73回応用物理学会秋季学術講演会  2012年9月 

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    開催年月日: 2012年9月

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  • 自己組織テンプレートを用いたナノワイヤ抵抗変化素子の形成と評価

    京見 拓也, 大塚 慎太郎, 武田 佳樹, 清水 智弘, 新宮原 正三

    第73回応用物理学会秋季学術講演会  2012年9月 

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    開催年月日: 2012年9月

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  • Au10クラスターの電子輸送特性

    小川 智矢, 深谷 一樹, 清水 智弘, 新宮原 正三, 齊藤 正, 稲田 貢

    第73回応用物理学会秋季学術講演会  2012年9月 

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    開催年月日: 2012年9月

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  • Large resistive switching phenomenon induced by magnetic field in nano conduction path formed in SiO2

    SHIMIZU T, OTUKA S, TAKASE K, SHINGUBARA S

    ICM 2012  2012年7月 

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    開催年月日: 2012年7月

    開催地:BUSAN, KOREA  

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  • Electrical properties of metal oxide nanowire formed in anodic aluminum oxide template

    SHIMIZU T, KYOMI T, OTSUKA S, TAKASE K, SHINGUBARA S

    ICPS 2012  2012年7月 

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    開催年月日: 2012年7月

    開催地:ZURICH, SWISS  

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  • All-wet Cu-filled TSV Process Using Electroless Co-alloy Barrier and Cu Seed

    INOUE F, SHIMIZU T, ARIMA R, MIYAKE H, SHINGUBARA S

    ECTC 2012  2012年5月 

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    開催年月日: 2012年5月

    開催地:San Diego, USA  

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  • Evaluation of crystal structure of porous Si nanowires prepared by metal assisted etching”

    YAMAGUCHI T, SHIMIZU T, WANG C, WANG Q, SHINGUBARA S, KUZNETSOV A, VANACKEN J, MOSHCHALKOV V

    MRS 2012  2012年5月 

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    開催年月日: 2012年5月

    開催地:Sun Francisco,USA  

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  • Electroless Deposition of Barrier and Seed Layers for Via Last Cu-TSV Metalization

    INOUE F, SHIMIZU T, ARIMA R, MIYAKE H, SHINGUBARA S

    IMFEDK 2012  2012年5月 

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    開催年月日: 2012年5月

    開催地:OSAKA, JAPAN  

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  • Low Temperature Through-Si Via Fabrication Using Electroless Deposition

    INOUE F, PHILIPSEN H, RADISIC A, AMNINI S, LEUNISSEN P, HMIYAKE H, ARIMA R, SHIMIZU T, ITO T, SEKI H, SHINOZAKI Y, YAMAMOTO T, SHINGUBARA S

    3DIC 2012  2012年2月 

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    開催年月日: 2012年2月

    開催地:OSAKA, JAPAN  

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産業財産権

  • 抵抗変化型メモリ及びその作製方法

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    出願番号:2012-176343  出願日:2012年8月

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共同研究・競争的資金等の研究課題

  • 電界印加による反強磁性-強磁性相転移の発現と不揮発性磁気メモリ応用

    研究課題/領域番号:21K04159  2021年4月 - 2024年3月

    日本学術振興会  科学研究費助成事業  基盤研究(C)

    岩田 展幸, 高瀬 浩一, 清水 智弘

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    配分額:4160000円 ( 直接経費:3200000円 、 間接経費:960000円 )

    CaFeOx(CFO)の酸化度が磁気特性に与える影響は大きい。CaFeO3(CFO3)から酸素欠損を起こした場合、CFO層内にはFe3+とFe4+が混在し強磁性的性質を示す。X線反射測定結果をフィッティングして、CFO3の存在比を見積もり以下の結果を得た。300Kにおける飽和磁化の大きさから、CFO3の存在比が約50%で緩やかなピークを示したことから、CFOの強磁性的性質を示唆していることがわかった。超格子では存在比が50%以下と低い値であったのに対し、積層膜では65%以上と非常に高い値であった。積層を続けることで、CFO3からの酸素欠損が上昇することがわかった。よって、反強磁性-強磁性転移を達成するには、積層膜が最適であると示唆する結果となった。
    一方、PLD成膜装置に装着されているターゲットマニピュレータの修理を行い、電気系統およびガス配管の整理・整備することで、事故を無くし操作性を改善して、連続成膜をより効率よく実施できるようになった。

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  • 制御可能なナノ構造を用いた微生物抗菌メカニズムの解明

    研究課題/領域番号:18K19008  2018年6月 - 2021年3月

    日本学術振興会  科学研究費助成事業  挑戦的研究(萌芽)

    伊藤 健, 小嶋 寛明, 新宮原 正三, 清水 智弘

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    配分額:6110000円 ( 直接経費:4700000円 、 間接経費:1410000円 )

    本研究では、ナノ構造が発現する抗菌メカニズムを解明するために、ナノ構造の寸法を制御すること、そしてその物理化学的性質を制御することでそれらのパラメーターが抗菌性に及ぼす影響について評価を行った。
    研究の結果、シリコン基板にナノピラーを任意の寸法で形成できる技術を開発し、それを用いて抗菌性を発現する構造的特徴を見出した。また、物理化学的条件も重要である事を見出した。

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  • 光触媒/多波長吸収金属ナノワイヤーコアシェルアレイによる可視光利用高効率水素生成

    研究課題/領域番号:18K04877  2018年4月 - 2023年3月

    日本学術振興会  科学研究費助成事業  基盤研究(C)

    高瀬 浩一, 清水 智弘, 田中 啓文

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    配分額:4290000円 ( 直接経費:3300000円 、 間接経費:990000円 )

    今年度も引き続き、金ナノワイヤーの作成をポーラスアルミナのナノ細孔を利用して行った。ポーラスアルミナの底部にはバリア層と呼ばれる絶縁層が存在するため、電解メッキにて金を埋め込むためには、このバリア層を除去しなければならない。バリア層除去のために、電圧降下処理とエッチング処理を併用した。これらを経て得られる金ナノワイヤーは、場所により長さが異なり、不均一である。また、バリア層を除去してもアルミニウムは直ちに酸化されてしまうので、再現性を得ることが大変困難である。これらの要因が妨げとなり、現在までに均一な長さをもつナノワイヤーの作成には至っていない。また、ナノワイヤーが成長する条件では、比較的長い1μm程度のワイヤーが成長することがほとんどであった。この試料の光学特性を評価した結果、金特有のプラズモン吸収がほとんど見られなかった。これは、長さが長いために、大半の部分はワイヤーの影になり、光が届いていないためであると推察される。
    以上のようなナノワイヤーであることは、承知の上で、原子層堆積法による酸化チタン膜でのナノワイヤーコーティングを実施した。これで、一様、目標とする酸化チタン/金なのワイヤーコアシェル構造を作成できた。得られた複合体が可視光のもと、水を分解できるかどうかを、暗室中でグリーンレーザーを光源に用い水分解実験を試みたところ、ガスの発生を確認できた。現状では、これらのガスが何であるか特定には至っていない。

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  • 多層膜金属触媒を用いた湿式シリコン基板垂直エッチング法の高精度制御に関する研究

    研究課題/領域番号:18K04916  2018年4月 - 2022年3月

    日本学術振興会  科学研究費助成事業  基盤研究(C)

    清水 智弘, 新宮原 正三, 伊藤 健

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    配分額:4420000円 ( 直接経費:3400000円 、 間接経費:1020000円 )

    貴金属触媒を用いた湿式エッチング法(Metal assisted chemical Etching: MacEtch)をシリコン基板のマイクロスケール加工技術に適用するためには、①貴金属触媒であるAuのSiへの拡散防止、②ランダムエッチングの発生防止という課題がある。これらの課題に対し、我々は貴金属触媒をAu単層構造からAu/Tiなど中間層金属を用いた多層金属構造を用いることでエッチング初期に起こるランダムエッチングの抑止に成功し、そのメカニズムを明らかにした。また、長時間のエッチング時に起こるランダムエッチングにおいては界面活性剤の添加が有効であることを示した。

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  • 空間制御型抵抗変化メモリの創成とスイッチングメカニズムの解明

    研究課題/領域番号:15K04602  2015年4月 - 2018年3月

    日本学術振興会  科学研究費助成事業  基盤研究(C)

    高瀬 浩一, 清水 智弘, 牧原 克典

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    配分額:4940000円 ( 直接経費:3800000円 、 間接経費:1140000円 )

    絶縁体ナノワイヤーを用いた抵抗変化メモリを作成し、そのスイッチング特性を調査した。このデバイスにおいては、絶縁体の直径が約40nm程度であるため、この中に作られる導電性フィラメントの数は制限されることになり、スイッチング電圧のばらつきが改善されると期待される。そこで、ポーラスアルミナをナノテンプレートとして電解メッキ法によりニッケルをナノ細孔に埋め込むことでニッケルナノワイヤーを作成し、その後、このナノワイヤーを酸化することで抵抗変化メモリを得た。
    このナノワイヤーを絶縁体とする抵抗変化メモリのスイッチング特性を調べた結果、通常の薄膜を用いたものに比べ、スイッチング電圧のばらつきは抑制された。

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  • CuSnナノツリーの形成機構の解明と制御及び超高性能ガスセンサ応用の研究

    研究課題/領域番号:25600048  2013年4月 - 2015年3月

    日本学術振興会  科学研究費助成事業  挑戦的萌芽研究

    新宮原 正三, 夛田 芳広, 清水 智弘

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    配分額:4030000円 ( 直接経費:3100000円 、 間接経費:930000円 )

    3次元的ナノツリー構造がCuSn合金の直流電解めっきによって形成されることを見出した。ナノツリーのそれぞれの枝は単結晶であり、(100)方向に伸びているものが殆どであり、また元素組成はCu:Sn=4:1程度である。結晶構造は立方晶であるが、周期的な面状欠陥を含む超格子構造が認められた。枝はすべてが直交して生えており、体積に対して表面積が著しく大きな構造となっている。本材料は酸化したのちには、高感度ガスセンサーやリチウムイオンバッテリーへの応用に適しているものと考えられる。大気中での酸化においては350℃にて、ナノツリーの構造を維持したまま酸化物が形成されることを確認した。

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  • 低環境負荷材料CZTSナノワイヤを用いた太陽電池の形成と評価

    研究課題/領域番号:25790024  2013年4月 - 2015年3月

    日本学術振興会  科学研究費助成事業  若手研究(B)

    清水 智弘

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    配分額:4290000円 ( 直接経費:3300000円 、 間接経費:990000円 )

    本研究では環境低負荷太陽電池CZTSの高エネルギー変換効率化を目指し、Siナノワイヤ配列を鋳型とし、その上にCZTS薄膜を形成することで、ナノシリンダーCZTS配列の形成を行った。シリンダーCZTS配列では通常の薄膜と比較し、高い光吸収係数と光電流値を示すことを確認した。さらに副次的な成果としてCZTS形成の際に、硫黄や毒物である硫化水素を用いず、比較的取り扱いが容易な硫化炭素によるCZTS硫化方法を見出した。これらの成果は高エネルギー変換効率かつ低環境負荷なCZTS太陽電池の実現に貢献できると考える。

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  • トップダウンとボトムアップ融合による超高密度ナノホール配列形成と磁気記録媒体応用

    研究課題/領域番号:20241027  2008年 - 2010年

    日本学術振興会  科学研究費助成事業  基盤研究(A)

    新宮原 正三, 田中 秀吉, 清水 智弘

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    配分額:26780000円 ( 直接経費:20600000円 、 間接経費:6180000円 )

    シリコン基板上へ形成した陽極酸化アルミナ・ナノホール配列を用いて、平方インチ当たりの密度200ギガから2.5テラの範囲の磁性体ナノロッド配列形成に成功した。ナノロッド最少直径は10nmであり、室温での保磁力は2.0kOeである。また、電子ビーム描画とエッチング、さらに陽極酸化自己組織化を組み合わせるトップダウンとボトムアップ融合により、ナノホール規則配列周期の縮小化に成功し、超高密度磁気記録媒体形成への指針を与えた。

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教育内容・方法の工夫(授業評価等を含む)

  • Webを利用した授業を行っている。 具体的には情報処理科目では授業資料の公開、課題解答例の公開などをWeb上(CEAS)で行っている。さらに質問の受付や課題の提出もWeb上で行い、授業が教員側からの一方通行にならないように心がけている。 さらに力学では講義だけにならないよう、TAを配置し、その日の講義内容の演習を行い、その場で疑問に感じたことやわからないことを質問させて理解を深める工夫をしている。

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